C-carboranylmethylmagnesium bromide

Base Information

Chemical Name:C-carboranylmethylmagnesium bromide
CAS No.:20199-64-8
Molecular Formula:C₃H₁₃B₁₀BrMg
Molecular Weight:261.455
Hs Code.:

Synonyms:C-carboranylmethylmagnesium bromide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of C-carboranylmethylmagnesium bromide

Chemical Property:

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Technology Process of C-carboranylmethylmagnesium bromide

There total 1 articles about C-carboranylmethylmagnesium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 19496-84-5
1-bromomethyl-1,2-dicarba-closo-dodecaborane⁽¹²⁾

: 7439-95-4
magnesium

: 16872-10-9
1-methyl-o-carborane

: 20199-64-8
C-carboranylmethylmagnesium bromide

: 17805-87-7
1-CH₃-2-MgBr-1.2-C₂B₁₀H₁₀

: 1-CH₂MgBr-2-MgBr-1.2-C₂B₁₀H₁₀

Guidance literature:: In diethyl ether; Grignard-react. in diethyl ether;;
DOI:10.1021/ic50010a008 DOI:10.1021/ic50010a009 DOI:10.1021/ic50010a004

Reference yield: 75.0%

: 20199-64-8
C-carboranylmethylmagnesium bromide

: ammonium chloride

: 107651-35-4
methyl 3,3,3-trifluoro-2-benzenesulfonyliminopropionate

: 737767-06-5
methyl N-(phenylsulfonyl)-α-(trifluoromethyl)-o-carboranylalaninate

Guidance literature:: In diethyl ether; water; soln. of imine in Et2O added dropwise at -70°C to Et2O soln. of Mg compd.; stirred at -70°C for 1 h; warmed slowly to 20°C;stirred for 6 h; treated with satd. aq. soln. of NH4Cl; extd. with Et2O; extracts dried (Na2SO4); solvent removed; purified by column chromy. (silica gel, hexane-ethyl acetate); elem. anal.;
DOI:10.1007/s11172-007-0118-9