Sodium 4-formylbenzenesulfonate

Base Information

• Chemical Name: Sodium 4-formylbenzenesulfonate
• CAS No.: 13736-22-6
• Molecular Formula: C7H5NaO4S
• Molecular Weight: 208.17
• Hs Code.: 2912299000
• Mol file: 13736-22-6.mol

Synonyms:Benzenesulfonicacid, 4-formyl-, sodium salt (9CI);Benzenesulfonic acid, p-formyl-, sodiumsalt (8CI);Sodium 4-formylbenzenesulfonate;Sodium benzaldehyde-p-sulfonate;Sodium p-formylbenzenesulfonate;

Chemical Property of Sodium 4-formylbenzenesulfonate

Chemical Property:

• Appearance/Colour: white crystal
• PSA: 82.65000
• LogP: 1.48400
• Storage Temp.: Hygroscopic, -20°C Freezer, Under inert atmosphere

Purity/Quality:

98%,99%, ^*data from raw suppliers

Sodium4-Formylbenzenesulfonate(~90%) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Sodium 4-formylbenzenesulfonate

There total 4 articles about Sodium 4-formylbenzenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium 4-styrenesulfonate (2695-37-6) → sodium 4-carboxy-benzenesulfonate (13736-22-6)

Guidance literature:

With ammonium cerium (IV) nitrate; [Ru(dmp)2(H₂O)2](PF₆)2; water-d2; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1039/c1cc12558c

Reference yield:

sodium 4-styrenesulfonate (2695-37-6) → sodium 4-carboxy-benzenesulfonate (13736-22-6) + sodium 4-(1,2-dihydroxyethyl)benzenesulfonate + sodium 4-(oxiranyl)benzenesulfonate

Guidance literature:

With tris(2,2’-bipyridine)ruthenium(II); laccase LAC₃ from Trametes sp. C₃₀; oxygen; for 6h; pH=6; pH-value; Reagent/catalyst; Irradiation; Inert atmosphere; Glovebox; Enzymatic reaction;

DOI:10.1002/cssc.201500602

Reference yield:

sodium 4-styrenesulfonate (2695-37-6) → sodium 4-carboxy-benzenesulfonate (13736-22-6) + sodium 4-(1,2-dihydroxyethyl)benzenesulfonate

Guidance literature:

With ammonium cerium (IV) nitrate; water-d2; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1039/c1cc12558c

upstream raw materials:

sodium 4-styrenesulfonate

Downstream raw materials:

4-(1,2,3,4-tetrahydroisoquinoline-2-sulfonyl)benzaldehyde

4-(morpholin-4-ylsulfonyl)benzaldehyde

Refernces

• 1、 Ohzu, Shingo,Ishizuka, Tomoya,Hirai, Yuichirou,Fukuzumi, Shunichi,Kojima, Takahiko. "Photocatalytic oxidation of organic compounds in water by using ruthenium(II)-pyridylamine complexes as catalysts with high efficiency and selectivity". . p. 1563 - 1567. Retrieved 2013.
• 2、 Schneider, Ludovic,Mekmouche, Yasmina,Rousselot-Pailley, Pierre,Simaan, A. Jalila,Robert, Viviane,Réglier, Marius,Aukauloo, Ally,Tron, Thierry. "Visible-Light-Driven Oxidation of Organic Substrates with Dioxygen Mediated by a [Ru(bpy)3]2+/Laccase System". . p. 3048 - 3051. Retrieved 2015.