cis-dicarbonyl-cis-dichloro-trans-bis(diphenyl(tetrahydro-2-furanylmethyl)phosphane-P)ruthenium(II)

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Chemical Name:cis-dicarbonyl-cis-dichloro-trans-bis(diphenyl(tetrahydro-2-furanylmethyl)phosphane-P)ruthenium(II)
CAS No.:109011-70-3
Molecular Formula:C₃₆H₃₈Cl₂O₄P₂Ru
Molecular Weight:768.619
Hs Code.:

Synonyms:cis-dicarbonyl-cis-dichloro-trans-bis(diphenyl(tetrahydro-2-furanylmethyl)phosphane-P)ruthenium(II)

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Chemical Property of cis-dicarbonyl-cis-dichloro-trans-bis(diphenyl(tetrahydro-2-furanylmethyl)phosphane-P)ruthenium(II)

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Technology Process of cis-dicarbonyl-cis-dichloro-trans-bis(diphenyl(tetrahydro-2-furanylmethyl)phosphane-P)ruthenium(II)

There total 3 articles about cis-dicarbonyl-cis-dichloro-trans-bis(diphenyl(tetrahydro-2-furanylmethyl)phosphane-P)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 14898-67-0
ruthenium(III) chloride trihydrate

: 91533-65-2
diphenyl(tetrahydro-2-furanylmethyl)phosphane

: 109011-70-3
cis-dicarbonyl-cis-dichloro-trans-bis(diphenyl(tetrahydro-2-furanylmethyl)phosphane-P)ruthenium(II)

Guidance literature:: With CO; In 2-methoxy-ethanol; Through a boiling soln. of RuCl3*3H2O CO is introduced for 5 h, to this mixt. a soln. of ligand-compd. is dropwise added (N2 or Ar).; Cooling to 6°C, monitored by (31)P NMR, 2 diastereomers, elem. anal.;

Reference yield: 92.0%

: 109011-61-2
trans-dichloro-cis-bis(diphenyl(tetrahydro-2-furanylmethyl)phosphane-O,P)ruthenium(II)

: 109011-70-3
cis-dicarbonyl-cis-dichloro-trans-bis(diphenyl(tetrahydro-2-furanylmethyl)phosphane-P)ruthenium(II)

Guidance literature:: With CO; In toluene; A soln. of Ru-compd. is refluxed under CO for 8 h.; Soln. is cooled to 20°C, pptn. with n-hexane, filtn., drying at 20°C in vac., monitored by (31)P NMR, 2 diastereomers, elem. anal.;