(E)-(5,5,5-trifluoro-4-(phenylsulfonyl)pent-1-enyl)benzene

Base Information

• Chemical Name: (E)-(5,5,5-trifluoro-4-(phenylsulfonyl)pent-1-enyl)benzene
• CAS No.: 1402748-62-2
• Molecular Formula: C₁₇H₁₅F₃O₂S
• Molecular Weight: 340.366
• Mol file: 1402748-62-2.mol

Synonyms:(E)-(5,5,5-trifluoro-4-(phenylsulfonyl)pent-1-enyl)benzene

Chemical Property of (E)-(5,5,5-trifluoro-4-(phenylsulfonyl)pent-1-enyl)benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-(5,5,5-trifluoro-4-(phenylsulfonyl)pent-1-enyl)benzene

There total 5 articles about (E)-(5,5,5-trifluoro-4-(phenylsulfonyl)pent-1-enyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

β,β,β-trifluoroethyl phenyl sulfone (56354-44-0) + ethyl (1-phenylallyl) carbonate (106625-70-1) → (E)-(5,5,5-trifluoro-4-(phenylsulfonyl)pent-1-enyl)benzene (1402748-62-2)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 60 ℃; for 22h; Inert atmosphere;

DOI:10.1016/j.tetlet.2012.09.094

Reference yield: 76.0%

β,β,β-trifluoroethyl phenyl sulfone (56354-44-0) + ethyl (E)-3-phenyl-2-propenyl carbonate (106625-69-8) → (E)-(5,5,5-trifluoro-4-(phenylsulfonyl)pent-1-enyl)benzene (1402748-62-2)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 60 ℃; for 22h; Solvent; Concentration; Time; Reagent/catalyst; Inert atmosphere;

DOI:10.1016/j.tetlet.2012.09.094

Reference yield: 76.0%

β,β,β-trifluoroethyl phenyl sulfone (56354-44-0) + ethyl (E)-3-phenyl-2-propenyl carbonate (106625-69-8) → ((1E,6E)-4-(phenylsulfonyl)-4-(trifluoromethyl)hepta-1,6-diene-1,7-diyl)dibenzene (1402748-84-8) + (E)-(5,5,5-trifluoro-4-(phenylsulfonyl)pent-1-enyl)benzene (1402748-62-2)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 60 ℃; for 22h; Time; Reagent/catalyst; Concentration; Inert atmosphere;

DOI:10.1016/j.tetlet.2012.09.094

upstream raw materials:

β,β,β-trifluoroethyl phenyl sulfone

ethyl (E)-3-phenyl-2-propenyl carbonate

ethyl (1-phenylallyl) carbonate

thiophenol

Downstream raw materials:

((1E,6E)-4-(phenylsulfonyl)-4-(trifluoromethyl)hepta-1,6-diene-1,7-diyl)dibenzene

1-methyl-4-((1E,6E)-7-phenyl-4-(phenylsulfonyl)-4-(trifluoromethyl)hepta-1,6-dienyl)benzene

(E)-(1-phenyl-4-(trifluoromethyl)hepta-1,6-dien-4-ylsulfonyl)benzene