HFe₄(CO)12BHAu(P(CH₃C₆H₄)3)

Base Information

Chemical Name:HFe₄(CO)12BHAu(P(CH₃C₆H₄)3)
CAS No.:141292-25-3
Molecular Formula:C₃₃H₂₃AuBFe₄O₁₂P
Molecular Weight:1073.68
Hs Code.:

HFe<sub>4</sub>(CO)12BHAu(P(CH<sub>3</sub>C<sub>6</sub>H<sub>4</sub>)3)

Synonyms:HFe₄(CO)12BHAu(P(CH₃C₆H₄)3)

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Chemical Property of HFe₄(CO)12BHAu(P(CH₃C₆H₄)3)

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Technology Process of HFe₄(CO)12BHAu(P(CH₃C₆H₄)3)

There total 2 articles about HFe₄(CO)12BHAu(P(CH₃C₆H₄)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 28978-10-1
chloro{tris(o-tolyl)phosphine}gold(I)

: (C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾*HFe₄(CO)12BH^(1-)

: 141292-25-3
HFe₄(CO)12BHAu(P(CH₃C₆H₄)3)

Guidance literature:: With TlPF₆; In dichloromethane; byproducts: (P(C6H5)3)2NPF6, TlCl; react. under Ar (Schlenk technique); addn. of CH2Cl2 to a mixture of Fe-complex and Au-compd. and TlPF6, stirring for 45 min; pptn. of byproducts by addn. of ether, filtration, evapn. of filtrate, centrifugal chromy. (Kieselgel), elution of first light green fraction with CH2Cl2-hexane (1:1);

Reference yield: 50.0%

: 28978-10-1
chloro{tris(o-tolyl)phosphine}gold(I)

: (C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾*HFe₄(CO)12BH^(1-)

: 141292-25-3
HFe₄(CO)12BHAu(P(CH₃C₆H₄)3)

: Au(P(CH₃C₆H₄)3)2⁽¹⁺⁾*(HFe₄(CO)12BH)2Au^(1-)=(Au(P(CH₃C₆H₄)3)2)((HFe₄(CO)12BH)2Au)

Guidance literature:: With TlPF₆; In dichloromethane; react. under Ar (Schlenk technique); addn. of CH2Cl2 to a mixture of Fe-complex, Au-compd. and TlPF6, stirring for 45 min (color change from red-brown to dark green-brown); addn. of Et2O, filtration, evapn. of filtrate, sepn. by centrifugal chromy. (Kieselgel), elution with CH2Cl2-hexane (1:1), 2. fraction is fused compd. (dark green), 1. fraction is unfused Au-compd.;

Reference yield: 95.0%

: 141292-25-3
HFe₄(CO)12BHAu(P(CH₃C₆H₄)3)

: 141319-38-2
(CH₃CH₂)3NH⁽¹⁺⁾*Fe₄(CO)12BHAu(P(CH₃C₆H₄)3)^(1-)=((CH₃CH₂)3NH)(Fe₄(CO)12BHAu(P(CH₃C₆H₄)3))

Guidance literature:: With (C₂H₅)3N; In dichloromethane; react. under Ar (Schlenk technique); addn. of Et3N to Fe-complex in CH2Cl2, 10 min in an ultrasonic bath (color change from light green to green-brown); evapn., washing with hexane, drying under reduced pressure;