Chloro[tri(p-tolyl)phosphine]gold(I),97%

Base Information

• Chemical Name: Chloro[tri(p-tolyl)phosphine]gold(I),97%
• CAS No.: 28978-10-1
• Molecular Formula: C21H20AuClP+
• Molecular Weight: 536.791
• Mol file: 28978-10-1.mol

Synonyms:Chloro[tri(4-methylphenyl)phosphine]gold(I)

Chemical Property of Chloro[tri(p-tolyl)phosphine]gold(I),97%

Chemical Property:

• Melting Point: 205-210°C
• PSA: 13.59000
• LogP: 1.37150
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

97% ^*data from raw suppliers

Chloro[tri(p-tolyl)phosphine]gold(I) 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Gold Catalysts — 21st Century ′Gold Rush′

Technology Process of Chloro[tri(p-tolyl)phosphine]gold(I),97%

There total 11 articles about Chloro[tri(p-tolyl)phosphine]gold(I),97% which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

hydrogen tetrachloroaurate(III) tetrahydrate + tris-(o-tolyl)phosphine (6163-58-2) → chloro{tris(o-tolyl)phosphine}gold(I) (28978-10-1)

Guidance literature:

hydrogen tetrachloroaurate(III) tetrahydrate; With propyl sulfide; In ethanol; at 40 ℃; for 0.166667h;

tris-(o-tolyl)phosphine; In ethanol; at 40 ℃; for 1h;

DOI:10.1021/ja311258e

Reference yield: 91.0%

chloroauric acid + tris-(o-tolyl)phosphine (6163-58-2) → chloro{tris(o-tolyl)phosphine}gold(I) (28978-10-1)

Guidance literature:

In ethanol; reaction in abs. EtOH; elem. anal.;

DOI:10.1039/DT9870002761

Reference yield: 90.0%

sodium tetrachloroaurate(III) (15189-51-2) + Tri(p-tolyl)phosphine (1038-95-5,218281-19-7) → (tri-p-tolylphosphine)gold(I) chloride (28978-10-1)

Guidance literature:

In not given; byproducts: (p-CH3C6H4)3PO; 2 equiv. of phosphine; elem. anal.;

DOI:10.1039/DT9790001730

upstream raw materials:

tris-(o-tolyl)phosphine

chloro(dimethylsulfide) gold(I)

HFe₄(CO)12BHAu(P(CH₃C₆H₄)3)

(tetrahydrothiophene)gold(I) chloride

Downstream raw materials:

{IrAuH₃(P(o-tol)3)(triphos)}{CF₃SO₃}

{IrAu₂H₃(P(o-tol)3)2(triphos)}{CF₃SO₃}2

N-indolyltri(2-tolyl)phosphinegold(I)

Ru₄(CO)12BHAu₂(P(CH₃C₆H₄)3)2