2,6-diiodo-4-heptafluoroisopropylaniline

Base Information

• Chemical Name: 2,6-diiodo-4-heptafluoroisopropylaniline
• CAS No.: 1152247-48-7
• Molecular Formula: C₉H₄F₇I₂N
• Molecular Weight: 512.935
• Mol file: 1152247-48-7.mol

Synonyms:2,6-diiodo-4-heptafluoroisopropylaniline

Chemical Property of 2,6-diiodo-4-heptafluoroisopropylaniline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,6-diiodo-4-heptafluoroisopropylaniline

There total 2 articles about 2,6-diiodo-4-heptafluoroisopropylaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

4-perfluoroisopropylaniline (2396-17-0) → 2,6-diiodo-4-heptafluoroisopropylaniline (1152247-48-7)

Guidance literature:

4-perfluoroisopropylaniline; With N-iodo-succinimide; sulfuric acid; In ethanol; at 5 - 20 ℃; for 3h;

With sodium hydrogencarbonate; In ethanol; water;

Reference yield:

aniline (62-53-3) → 2,6-diiodo-4-heptafluoroisopropylaniline (1152247-48-7)

Guidance literature:

Multi-step reaction with 2 steps

1: tetra(n-butyl)ammonium hydrogensulfate; sodium hydrogencarbonate; sodium dithionite / ethyl acetate; water / 6 h / 20 °C

2: sulfuric acid; N-iodo-succinimide / ethanol / 3 h / 5 - 20 °C

With N-iodo-succinimide; sodium dithionite; sulfuric acid; tetra(n-butyl)ammonium hydrogensulfate; sodium hydrogencarbonate; In ethanol; water; ethyl acetate;

Reference yield: 99.0%

2,6-diiodo-4-heptafluoroisopropylaniline (1152247-48-7) + 2-chloro-3-nitro-benzoyl chloride (34128-16-0) → 2-chloro-N-(2,6-diiodo-4-(perfluoropropan-2-yl)phenyl)-3-nitrobenzamide (1207315-60-3)

Guidance literature:

With 1,3-dimethyl-2-imidazolidinone; at 135 ℃; for 3h;

upstream raw materials:

4-perfluoroisopropylaniline

aniline

Downstream raw materials:

4-(1,1,1,3,3,3-hexafluoro-2-methoxypropan-2-yl)-2,6-diiodoaniline

2-chloro-N-(2,6-diiodo-4-(perfluoropropan-2-yl)phenyl)-3-nitrobenzamide

Refernces

• 1、 -. "AMIDE DERIVATIVE, PEST CONTROL AGENT CONTAINING THE AMIDE DERIVATIVE AND PEST CONTROLLING METHOD". Page/Page column 452; 453. . Retrieved 2011/06/24.