(((4S,5R,6R)-5-(benzyloxy)-2,2-dimethyl-6-(prop-1-en-2-yl)-1,3-dioxan-4-yl)methoxy)(tert-butyl)diphenylsilane

Base Information

Chemical Name:(((4S,5R,6R)-5-(benzyloxy)-2,2-dimethyl-6-(prop-1-en-2-yl)-1,3-dioxan-4-yl)methoxy)(tert-butyl)diphenylsilane
CAS No.:1314230-29-9
Molecular Formula:C₃₃H₄₂O₄Si
Molecular Weight:530.78
Hs Code.:

Synonyms:(((4S,5R,6R)-5-(benzyloxy)-2,2-dimethyl-6-(prop-1-en-2-yl)-1,3-dioxan-4-yl)methoxy)(tert-butyl)diphenylsilane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (((4S,5R,6R)-5-(benzyloxy)-2,2-dimethyl-6-(prop-1-en-2-yl)-1,3-dioxan-4-yl)methoxy)(tert-butyl)diphenylsilane

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Technology Process of (((4S,5R,6R)-5-(benzyloxy)-2,2-dimethyl-6-(prop-1-en-2-yl)-1,3-dioxan-4-yl)methoxy)(tert-butyl)diphenylsilane

There total 5 articles about (((4S,5R,6R)-5-(benzyloxy)-2,2-dimethyl-6-(prop-1-en-2-yl)-1,3-dioxan-4-yl)methoxy)(tert-butyl)diphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 1314230-28-8
(2S,3R,4R)-3-(benzyloxy)-1-(tert-butyldiphenylsilyloxy)-5-methylhex-5-ene-2,4-diol

: 77-76-9
2,2-dimethoxy-propane

: 1314230-29-9
(((4S,5R,6R)-5-(benzyloxy)-2,2-dimethyl-6-(prop-1-en-2-yl)-1,3-dioxan-4-yl)methoxy)(tert-butyl)diphenylsilane

Guidance literature:: With (1S)-10-camphorsulfonic acid; In dichloromethane;
DOI:10.1021/jo200396q

Reference yield:

: 1314230-27-7
(3aR,5R,6R,6aR)-6-(benzyloxy)-2,2-dimethyl-5-(prop-1-en-2-yl)tetrahydrofuro[2,3-d][1,3]dioxole

: 1314230-29-9
(((4S,5R,6R)-5-(benzyloxy)-2,2-dimethyl-6-(prop-1-en-2-yl)-1,3-dioxan-4-yl)methoxy)(tert-butyl)diphenylsilane

Guidance literature:: Multi-step reaction with 4 steps

1: trifluoroacetic acid / water / 3 h / 0 - 20 °C

2: lithium borohydride / tetrahydrofuran; methanol / 3 h / 0 - 20 °C

3: dmap; triethylamine / dichloromethane / 12 h / 0 - 20 °C

4: (1S)-10-camphorsulfonic acid / dichloromethane

With dmap; lithium borohydride; (1S)-10-camphorsulfonic acid; triethylamine; trifluoroacetic acid; In tetrahydrofuran; methanol; dichloromethane; water;
DOI:10.1021/jo200396q

Reference yield:

: C₁₄H₁₈O₄

: 1314230-29-9
(((4S,5R,6R)-5-(benzyloxy)-2,2-dimethyl-6-(prop-1-en-2-yl)-1,3-dioxan-4-yl)methoxy)(tert-butyl)diphenylsilane

Guidance literature:: Multi-step reaction with 3 steps

1: lithium borohydride / tetrahydrofuran; methanol / 3 h / 0 - 20 °C

2: dmap; triethylamine / dichloromethane / 12 h / 0 - 20 °C

3: (1S)-10-camphorsulfonic acid / dichloromethane

With dmap; lithium borohydride; (1S)-10-camphorsulfonic acid; triethylamine; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/jo200396q