1-<(2-isopropenyl)phenyl>-10,10-dimethyl-5,10-dihydrodibenzophosphorin

Base Information

Chemical Name:1-<(2-isopropenyl)phenyl>-10,10-dimethyl-5,10-dihydrodibenzophosphorin
CAS No.:96913-33-6
Molecular Formula:C₂₄H₂₃P
Molecular Weight:342.42
Hs Code.:

1-<(2-isopropenyl)phenyl>-10,10-dimethyl-5,10-dihydrodibenzo<b,e>phosphorin

Synonyms:1-<(2-isopropenyl)phenyl>-10,10-dimethyl-5,10-dihydrodibenzophosphorin

Suppliers and Price of 1-<(2-isopropenyl)phenyl>-10,10-dimethyl-5,10-dihydrodibenzophosphorin

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-<(2-isopropenyl)phenyl>-10,10-dimethyl-5,10-dihydrodibenzophosphorin

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-<(2-isopropenyl)phenyl>-10,10-dimethyl-5,10-dihydrodibenzophosphorin

There total 7 articles about 1-<(2-isopropenyl)phenyl>-10,10-dimethyl-5,10-dihydrodibenzophosphorin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 96897-86-8
1-<2-(1-hydroxy-1-methylethyl)phenyl>-10,10-dimethyl-5,10-dihydrodibenzophosphorin

: 96913-33-6
1-<(2-isopropenyl)phenyl>-10,10-dimethyl-5,10-dihydrodibenzophosphorin

Guidance literature:: With methanesulfonic acid; phosphorus pentoxide; for 1h; Ambient temperature;
DOI:10.1021/jo00216a021

Reference yield:

: 824-72-6
P,P-dichlorophenylphosphine oxide

: 96913-33-6
1-<(2-isopropenyl)phenyl>-10,10-dimethyl-5,10-dihydrodibenzophosphorin

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) t-BuLi / 1.) THF, T<-60 deg C, 10 min, 2.) THF, 1 h

2: 86 percent / 2 N HCl / ethanol / Ambient temperature

3: 86 percent / 115percent polyphosphoric acid (PPA) / 0.5 h / 150 - 155 °C

4: 83 percent / HSiCl₃ / benzene / 5 h / Heating

5: 89 percent / 10percent P₂O₅/methanesulfonic acid (MSA) / 1 h / Ambient temperature

With hydrogenchloride; PPA; methanesulfonic acid; trichlorosilane; tert.-butyl lithium; phosphorus pentoxide; In ethanol; benzene;
DOI:10.1021/jo00216a021

Reference yield:

: 71433-47-1
3,3,3',3'-tetramethyl-1-phenyl-1,1'-spirobi<3H-2,1-benzoxaphosphole>

: 96913-33-6
1-<(2-isopropenyl)phenyl>-10,10-dimethyl-5,10-dihydrodibenzophosphorin

Guidance literature:: Multi-step reaction with 3 steps

1: 86 percent / 115percent polyphosphoric acid (PPA) / 0.5 h / 150 - 155 °C

2: 83 percent / HSiCl₃ / benzene / 5 h / Heating

3: 89 percent / 10percent P₂O₅/methanesulfonic acid (MSA) / 1 h / Ambient temperature

With PPA; methanesulfonic acid; trichlorosilane; phosphorus pentoxide; In benzene;
DOI:10.1021/jo00216a021