tricyclohexyl(4-vinylbenzyl)phosphonium chloride

Base Information

Chemical Name:tricyclohexyl(4-vinylbenzyl)phosphonium chloride
CAS No.:1017623-18-5
Molecular Formula:C₂₇H₄₂P*Cl
Molecular Weight:433.057
Hs Code.:

Synonyms:tricyclohexyl(4-vinylbenzyl)phosphonium chloride

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Chemical Property of tricyclohexyl(4-vinylbenzyl)phosphonium chloride

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Technology Process of tricyclohexyl(4-vinylbenzyl)phosphonium chloride

There total 1 articles about tricyclohexyl(4-vinylbenzyl)phosphonium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 1592-20-7,29296-32-0
4-Vinylbenzyl chloride

: 2622-14-2
tricyclohexylphosphine

: 1017623-18-5
tricyclohexyl(4-vinylbenzyl)phosphonium chloride

Guidance literature:: In acetonitrile; at 80 ℃; for 72h;
DOI:10.1021/ja078149z

Reference yield: 67.0%

: 246047-72-3
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

: 1017623-18-5
tricyclohexyl(4-vinylbenzyl)phosphonium chloride

: ((C₆H₁₁)3P)(C₃H₄N₂(C₆H₂(CH₃)3)2)RuCl₂(CHC₆H₄CH₂P(C₆H₁₁)3)⁽¹⁺⁾*Cl^(1-)=((C₆H₁₁)3P)RuCl₂(C₈H₇P(C₆H₁₁)3)(C₃H₄N₂(C₉H₁₁)2)Cl

Guidance literature:: In dichloromethane; byproducts: styrene; (Ar, Schlenk) the mixt. in CH2Cl2 was stirred at room temp. for 20 min; the solvent was removed in vac., the formed styrene was coevapd. with 1,2-dichlorobenzene, CH2Cl2 was added to remove 1,2-dichlorobenzene, the residue was dried in vac. overnight, diethyl ether was added to CH2Cl2-soln., filtered, dried in vac.;
DOI:10.1021/ja078149z

Reference yield: 64.0%

: Grubbs catalyst first generation

: 1017623-18-5
tricyclohexyl(4-vinylbenzyl)phosphonium chloride

: ((C₆H₁₁)3P)2RuCl₂(CHC₆H₄CH₂P(C₆H₁₁)3)⁽¹⁺⁾*Cl^(1-)=((C₆H₁₁)3P)2RuCl₂(CHC₆H₄CH₂P(C₆H₁₁)3)Cl

Guidance literature:: In dichloromethane; byproducts: styrene; (Ar, Schlenk) the mixt. in CH2Cl2 was stirred at room temp. for 20 min; the solvent was removed in vac., the formed styrene was coevapd. with 1,2-dichlorobenzene, CH2Cl2 was added to remove 1,2-dichlorobenzene, the residue was dried in vac. overnight, diethyl ether was added to CH2Cl2-soln., filtered, dried in vac.;
DOI:10.1021/ja078149z