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1-(Chloromethyl)-4-vinylbenzene

Base Information Edit
  • Chemical Name:1-(Chloromethyl)-4-vinylbenzene
  • CAS No.:1592-20-7
  • Molecular Formula:C9H9Cl
  • Molecular Weight:152.623
  • Hs Code.:29039990
  • European Community (EC) Number:216-471-2
  • UNII:CJL4OJ6BS0
  • DSSTox Substance ID:DTXSID2061808
  • Nikkaji Number:J91.309J
  • Wikipedia:4-Vinylbenzyl_chloride
  • Wikidata:Q28096079
  • Mol file:1592-20-7.mol
1-(Chloromethyl)-4-vinylbenzene

Synonyms:4-Vinylbenzyl chloride;1592-20-7;1-(Chloromethyl)-4-vinylbenzene;1-(chloromethyl)-4-ethenylbenzene;4-(Chloromethyl)styrene;4-Chloromethylstyrene;Benzene, 1-(chloromethyl)-4-ethenyl-;p-vinylbenzyl chloride;CJL4OJ6BS0;EINECS 216-471-2;MFCD00051362;4-Vinylbenzyl chloride,contains 0.1% total stabilizer;p-chloromethylstyrene;4-vinyl benzylchloride;p-(chloromethyl)styrene;(4-vinylbenzyl)chloride;4-vinyl benzyl chloride;UNII-CJL4OJ6BS0;SCHEMBL35299;1-chloromethyl-4-vinylbenzene;4-Vinylbenzyl chloride, 90%;1-(chloromethyl)4-vinylbenzene;DTXSID2061808;1-(chloromethyl)-4-ethenyl-benzen;Vinylbenzyl Chloride (vbc) Monomer;AMY40230;1-(Chloromethyl)-4-vinylbenzene #;STL183304;AKOS006221481;FS-4211;C1792;FT-0658977;D78363;Vinylbenzylchloride;(4-Vinylbenzyl chloride);J-017738;W-107987;1-(Chloromethyl)-4-vinylbenzene, 500 ppm t-Butylcatechol inhibitor;4-Chloromethylstyrene, 90% stabilized with TBC+ONP+o-nitrocresol;4-(Chloromethyl)styrene (stabilized with TBC + ONP + 2-Nitro-p-cresol);1-(Chloromethyl)-4-vinylbenzene (stabilised with TBC + ONP + 2-Nitro-p-cresol);4-Vinylbenzyl chloride, technical, >=90% (GC), contains 0.1% total stabilizer

Suppliers and Price of 1-(Chloromethyl)-4-vinylbenzene
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • TRC
  • 4-(Chloromethyl)styrene(~0.1%TBCstabilizer)
  • 10g
  • $ 45.00
  • TRC
  • 4-(Chloromethyl)styrene(~0.1%TBCstabilizer)
  • 25g
  • $ 80.00
  • TCI Chemical
  • 4-(Chloromethyl)styrene (stabilized with TBC + ONP + 2-Nitro-p-cresol) >90.0%(GC)
  • 25g
  • $ 47.00
  • TCI Chemical
  • 4-(Chloromethyl)styrene (stabilized with TBC + ONP + 2-Nitro-p-cresol) >90.0%(GC)
  • 250g
  • $ 265.00
  • SynQuest Laboratories
  • 4-Vinylbenzylchloride,technicalgrade
  • 250 g
  • $ 400.00
  • SynQuest Laboratories
  • 4-Vinylbenzylchloride,technicalgrade
  • 25 g
  • $ 96.00
  • Sigma-Aldrich
  • 4-Vinylbenzyl chloride 90%
  • 25ml
  • $ 37.50
  • Sigma-Aldrich
  • 4-Vinylbenzyl chloride 90%
  • 100ml
  • $ 55.10
  • Sigma-Aldrich
  • 4-Vinylbenzyl chloride technical, ≥90% (GC), contains 0.1% total stabilizer
  • 50ml
  • $ 140.00
  • Sigma-Aldrich
  • 4-Vinylbenzyl chloride technical, ≥90% (GC), contains 0.1% total stabilizer
  • 250ml
  • $ 495.00
Total 156 raw suppliers
Chemical Property of 1-(Chloromethyl)-4-vinylbenzene Edit
Chemical Property:
  • Appearance/Colour:clear yellow liquid 
  • Vapor Pressure:1 mm Hg ( 56.1 °C) 
  • Refractive Index:n20/D 1.572(lit.)  
  • Boiling Point:228.9 °C at 760 mmHg 
  • Flash Point:90.4 °C 
  • PSA:0.00000 
  • Density:1.066 g/cm3 
  • LogP:3.06840 
  • Storage Temp.:−20°C 
  • Water Solubility.:Insoluble in water 
  • XLogP3:3.1
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:0
  • Rotatable Bond Count:2
  • Exact Mass:152.0392780
  • Heavy Atom Count:10
  • Complexity:101
Purity/Quality:

95% *data from raw suppliers

4-(Chloromethyl)styrene(~0.1%TBCstabilizer) *data from reagent suppliers

Safty Information:
  • Pictogram(s): Corrosive
  • Hazard Codes:
  • Statements: 34-43-21/22 
  • Safety Statements: 26-36/37/39-45 
MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:
  • Chemical Classes:Other Classes -> Halogenated Monoaromatics
  • Canonical SMILES:C=CC1=CC=C(C=C1)CCl
  • Uses Component of ion exchange resins, photo-resist polymers, cross-linkable fibers, coupling agents and electroconducting polymers.Starter for various copolymer preparations.Dual functional monomer. Readily derivatized by chloride displacement.
Technology Process of 1-(Chloromethyl)-4-vinylbenzene

There total 16 articles about 1-(Chloromethyl)-4-vinylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With 18-crown-6 ether; potassium hydroxide; In toluene; at 40 ℃; for 4h; Reagent/catalyst; Temperature; Solvent;
Guidance literature:
With oxalyl dichloride; Tropone; In dichloromethane; at 20 ℃; for 0.25h; Inert atmosphere;
DOI:10.1021/ol5003972
Guidance literature:
With 4-tert-Butylcatechol; sodium t-butanolate; In tetrahydrofuran; at 30 ℃; for 1h; Reagent/catalyst; Solvent; Inert atmosphere;
Refernces Edit

Effect of surfactant architecture on the properties of polystyrene- montmorillonite nanocomposites

10.1021/la904827d

The study investigates the influence of surfactant architecture on the properties of polystyrene-montmorillonite (PS-MMT) nanocomposites. A variety of surfactants were designed and synthesized to modify clay, aiming to understand how their chemical structure affects the nanocomposite's morphology after polymerization. The research focused on the behavior of surfactant-modified clays at three stages: post ion-exchange, after dispersion in styrene monomer, and following polymerization. The compatibility and prediction of the nanocomposite morphology were assessed based on the styrene monomer's ability to swell the surfactant-modified clay. Key factors identified for achieving exfoliated morphologies included the position of the ammonium group, the presence of a polymerizable group, surfactant solubility in the monomer, the length of the alkyl chain, and the concentration of surfactant used for clay modification. Techniques such as small-angle X-ray scattering (SAXS), cryogenic transmission electron microscopy (cryo-TEM), wide-angle X-ray scattering (WAXS), dynamic mechanical thermal analysis (DMTA), and thermal gravimetric analysis (TGA) were utilized to characterize the clay-polymer interactions and the properties of the resulting composites. The findings are expected to enhance the design of clay modifications for polymer nanocomposites.

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