3-(tert-Butyl-dimethyl-silanyloxy)-2-diazo-but-3-enoic acid 4-benzyloxymethyl-furan-3-ylmethyl ester

Base Information

Chemical Name:3-(tert-Butyl-dimethyl-silanyloxy)-2-diazo-but-3-enoic acid 4-benzyloxymethyl-furan-3-ylmethyl ester
CAS No.:287239-68-3
Molecular Formula:C₂₃H₃₀N₂O₅Si
Molecular Weight:442.587
Hs Code.:

Synonyms:3-(tert-Butyl-dimethyl-silanyloxy)-2-diazo-but-3-enoic acid 4-benzyloxymethyl-furan-3-ylmethyl ester

Suppliers and Price of 3-(tert-Butyl-dimethyl-silanyloxy)-2-diazo-but-3-enoic acid 4-benzyloxymethyl-furan-3-ylmethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-(tert-Butyl-dimethyl-silanyloxy)-2-diazo-but-3-enoic acid 4-benzyloxymethyl-furan-3-ylmethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-(tert-Butyl-dimethyl-silanyloxy)-2-diazo-but-3-enoic acid 4-benzyloxymethyl-furan-3-ylmethyl ester

There total 4 articles about 3-(tert-Butyl-dimethyl-silanyloxy)-2-diazo-but-3-enoic acid 4-benzyloxymethyl-furan-3-ylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 287241-59-2
3-benzyloxymethyl-4-furanmethanol

: 287239-68-3
3-(tert-Butyl-dimethyl-silanyloxy)-2-diazo-but-3-enoic acid 4-benzyloxymethyl-furan-3-ylmethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / acetonitrile / 1.5 h / 20 °C

2: 84 percent / p-ABSA; Et₃N / acetonitrile / 3 h / 20 °C

3: triethylamine / CH₂Cl₂ / 0 °C

With pyridine; 4-acetamidobenzenesulfonyl azide; triethylamine; In dichloromethane; acetonitrile; 1: Ring cleavage / 2: Diazotization / 3: silylation;
DOI:10.1021/jo991959b

Reference yield:

: 287241-64-9
4-benzyloxymethyl-3-furanylmethyl 3-oxobutanoate

: 287239-68-3
3-(tert-Butyl-dimethyl-silanyloxy)-2-diazo-but-3-enoic acid 4-benzyloxymethyl-furan-3-ylmethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / p-ABSA; Et₃N / acetonitrile / 3 h / 20 °C

2: triethylamine / CH₂Cl₂ / 0 °C

With 4-acetamidobenzenesulfonyl azide; triethylamine; In dichloromethane; acetonitrile; 1: Diazotization / 2: silylation;
DOI:10.1021/jo991959b

Reference yield:

: 14496-24-3
3,4-bis(hydroxymethyl)furan

: 287239-68-3
3-(tert-Butyl-dimethyl-silanyloxy)-2-diazo-but-3-enoic acid 4-benzyloxymethyl-furan-3-ylmethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 30 percent / NaH / tetrahydrofuran; various solvent(s) / 5 h / 20 °C

2: pyridine / acetonitrile / 1.5 h / 20 °C

3: 84 percent / p-ABSA; Et₃N / acetonitrile / 3 h / 20 °C

4: triethylamine / CH₂Cl₂ / 0 °C

With pyridine; 4-acetamidobenzenesulfonyl azide; sodium hydride; triethylamine; In tetrahydrofuran; dichloromethane; acetonitrile; 1: Substitution / 2: Ring cleavage / 3: Diazotization / 4: silylation;
DOI:10.1021/jo991959b