1α.2β.3α-Trihydroxy-1β-hydroxymethyl-cyclohexan

Base Information

Chemical Name:1α.2β.3α-Trihydroxy-1β-hydroxymethyl-cyclohexan
CAS No.:17550-45-7
Molecular Formula:C₇H₁₄O₄
Molecular Weight:162.186
Hs Code.:

Synonyms:1α.2β.3α-Trihydroxy-1β-hydroxymethyl-cyclohexan

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Chemical Property of 1α.2β.3α-Trihydroxy-1β-hydroxymethyl-cyclohexan

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Technology Process of 1α.2β.3α-Trihydroxy-1β-hydroxymethyl-cyclohexan

There total 8 articles about 1α.2β.3α-Trihydroxy-1β-hydroxymethyl-cyclohexan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (1R,5R,6S)-5,6-Bis-benzyloxy-1-benzyloxymethyl-cyclohex-3-enol

: 17550-45-7
1α.2β.3α-Trihydroxy-1β-hydroxymethyl-cyclohexan

Guidance literature:: With hydrogen; palladium on activated charcoal; In methanol; for 24h; under 37503 Torr; Yield given;
DOI:10.1016/S0040-4039(98)02539-8

Reference yield:

: 160549-10-0
2,3,5-tri-O-benzyl-D-arabinofuranose

: 17550-45-7
1α.2β.3α-Trihydroxy-1β-hydroxymethyl-cyclohexan

Guidance literature:: Multi-step reaction with 7 steps

1: 92 percent / BuLi / tetrahydrofuran / 0 - 20 °C

2: 87 percent / CrO₃, pyridine / CH₂Cl₂ / 0 deg C, 30 min then rt., 16 h

3: 97 percent / tetrahydrofuran / 16 h / -78 - 20 °C

4: 82 percent / 2,6-lutidine / 16 h / Ambient temperature

5: 19 percent / PhMe₂CCH=Mo=N<2,6-(i-Pr)2C₆H₃>3)2>2 / benzene / 16 h / Ambient temperature

6: Bu₄NF / tetrahydrofuran / 16 h / -20 - 0 °C

7: H₂ / Pd/C / methanol / 24 h / 37503 Torr

With pyridine; 2,6-dimethylpyridine; chromium(VI) oxide; n-butyllithium; tetrabutyl ammonium fluoride; hydrogen; palladium on activated charcoal; bis[1,1-di(trifluoromethyl)ethoxy][(2,6-diisopropylphenyl)imino](2-methyl-2-phenylpropylidene)molybdenum; In tetrahydrofuran; methanol; dichloromethane; benzene;
DOI:10.1016/S0040-4039(98)02539-8

Reference yield:

: 220939-94-6
(3S,4R)-1,3,4-tris(benzyloxy)-hex-5-en-2-one

: 17550-45-7
1α.2β.3α-Trihydroxy-1β-hydroxymethyl-cyclohexan

Guidance literature:: Multi-step reaction with 5 steps

1: 97 percent / tetrahydrofuran / 16 h / -78 - 20 °C

2: 82 percent / 2,6-lutidine / 16 h / Ambient temperature

3: 19 percent / PhMe₂CCH=Mo=N<2,6-(i-Pr)2C₆H₃>3)2>2 / benzene / 16 h / Ambient temperature

4: Bu₄NF / tetrahydrofuran / 16 h / -20 - 0 °C

5: H₂ / Pd/C / methanol / 24 h / 37503 Torr

With 2,6-dimethylpyridine; tetrabutyl ammonium fluoride; hydrogen; palladium on activated charcoal; bis[1,1-di(trifluoromethyl)ethoxy][(2,6-diisopropylphenyl)imino](2-methyl-2-phenylpropylidene)molybdenum; In tetrahydrofuran; methanol; benzene;
DOI:10.1016/S0040-4039(98)02539-8