220939-94-6

Basic information

• Product Name: (3S,4R)-1,3,4-tris(benzyloxy)-hex-5-en-2-one
• Synonyms: (3S,4R)-1,3,4-tris(benzyloxy)-hex-5-en-2-one
• CAS NO: 220939-94-6
• Molecular Weight: 416.517
• Mol File: 220939-94-6.mol

Chemical Properties

• CAS DataBase Reference: (3S,4R)-1,3,4-tris(benzyloxy)-hex-5-en-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4R)-1,3,4-tris(benzyloxy)-hex-5-en-2-one(220939-94-6)
• EPA Substance Registry System: (3S,4R)-1,3,4-tris(benzyloxy)-hex-5-en-2-one(220939-94-6)

Safety Data

• Hazardous Substances Data: 220939-94-6(Hazardous Substances Data)

Upstream product

• 102208-53-7 (3R,4R,5R)-5-hydroxy-3,4,6-tribenzyloxy-1-hexene 
• 160549-10-0 2,3,5-tri-O-benzyl-D-arabinofuranose 

Downstream Products

• 507238-34-8 (3R,4S)-3,4-dibenzyloxy-5-(benzyloxymethyl)deca-1,9-dien-5-ol 
• 909801-45-2 (2R,3R,4R)-1,3,4-Tris(benzyloxy)-N-(but-3-en-1-yl)hex-5-en-2-amine 
• 909801-43-0 2,3,5-tri-O-benzyl-1,4-benzylimino-1,4-dideoxy-D-arabinitol 
• 134307-35-0 2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-imino-N-benzyl-L-xylitol 
• 1054620-36-8 N-((1S,2S,3R,4S,5S)-3,4-Bis-benzyloxy-5-benzyloxymethyl-2,5-dihydroxy-cyclohexyl)-4-methyl-benzenesulfonamide 
• 220939-97-9 ((1S,5R,6S)-5,6-Bis-benzyloxy-1-benzyloxymethyl-cyclohex-3-enyloxy)-trimethyl-silane 
• 220939-98-0 ((1R,5R,6S)-5,6-Bis-benzyloxy-1-benzyloxymethyl-cyclohex-3-enyloxy)-trimethyl-silane 
• 220940-00-1 (1S,5R,6S)-5,6-Bis-benzyloxy-1-benzyloxymethyl-cyclohex-3-enol 
• 83465-22-9 (1S,2S,3R,4S,5S)-1-amino-5-hydroxymethyl-2,3,4,5-tetrahydroxycyclohexane 
• 17550-45-7 1α.2β.3α-Trihydroxy-1β-hydroxymethyl-cyclohexan 
• 244271-46-3 ((1S,2S,3R)-2,3-Bis-benzyloxy-1-benzyloxymethyl-1-vinyl-pent-4-enyloxy)-trimethyl-silane 
• 244271-47-4 ((1S,4R,5S)-4,5-Bis-benzyloxy-1-benzyloxymethyl-cyclopent-2-enyloxy)-trimethyl-silane 
• 244271-49-6 Acetic acid (1S,4R,5S)-4,5-bis-benzyloxy-1-benzyloxymethyl-cyclopent-2-enyl ester 

Relevant articles and documents

Ring closing metathesis as an efficient approach to branched cyclitols and aminocyclitols: A short synthesis of valiolamine

Ring closing metathesis of sugar-derived 1,6 dienes is the key step for the construction of highly functionnalized cyclohexenes, precursors of branched cyclitols and aminocyclitols. The method has been used for a short synthesis of valiolamine.

Efficient synthesis of 8-oxa-bicyclo[3.2.1]octane derivatives from d-arabinose

Our studies of the TIBAL-promoted Claisen rearrangement reaction and ring-closing metathesis (RCM) resulted in the development of an efficient synthetic route to polyfunctional seven-membered carbasugar synthons from d-arabinose. Moreover, the constructio

Synthesis of naturally occurring iminosugars from d-fructose by the use of a zinc-mediated fragmentation reaction

A short synthesis of 1,4-dideoxy-1,4-imino-d-arabinitol (DAB) and a formal synthesis of australine are described. In both cases, d-fructose is employed as the starting material and converted into a protected methyl 6-deoxy-6-iodo- furanoside. Zinc-mediate

A polyhydroxylated cyclopentene: A useful synthon toward the synthesis of carbocyclic D-fructofuranoid

A polyhydroxylated cyclopentene has been synthesized in five steps with an overall yield of 61%, starting from 2,3,5-tri-O-benzyl-D-arabinofuranose.

The Utility of 2,5-Dideoxy-2,5-imino-D-mannitol as a PFP Enzyme Inhibitor

2,5-Dideoxy-2,5-imino-D-mannitol was synthesized from an arabinofuranose derivative.Mercuric acetate cyclization of an ene-carbamate was the key step.The compound proved to be an inhibitor of the pyrophosphate-fructose-6-phosphate-1-phosphotransferase (PFP) enzyme and has potential utility in the biorational design of herbicides.