[Ru(2,2′-bipyridine)₂(1,2-bis(phenylthio)ethane)](PF₆)₂

Base Information

Chemical Name:[Ru(2,2′-bipyridine)₂(1,2-bis(phenylthio)ethane)](PF₆)₂
CAS No.:97278-96-1
Molecular Formula:C₃₄H₃₀N₄RuS₂*2F₆P
Molecular Weight:949.769
Hs Code.:

[Ru(2,2′-bipyridine)<sub>2</sub>(1,2-bis(phenylthio)ethane)](PF<sub>6</sub>)<sub>2</sub>

Synonyms:[Ru(2,2′-bipyridine)₂(1,2-bis(phenylthio)ethane)](PF₆)₂

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Chemical Property of [Ru(2,2′-bipyridine)₂(1,2-bis(phenylthio)ethane)](PF₆)₂

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Technology Process of [Ru(2,2′-bipyridine)₂(1,2-bis(phenylthio)ethane)](PF₆)₂

There total 3 articles about [Ru(2,2′-bipyridine)₂(1,2-bis(phenylthio)ethane)](PF₆)₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 26042-63-7
silver(I) hexafluorophosphate

: 31765-78-3
cis-bis(2,2′-bipyridine)dichlororuthenium(II) hydrate

: 622-20-8
1,2-bis(phenylthio)ethane

: 97278-96-1
[Ru(2,2′-bipyridine)₂(1,2-bis(phenylthio)ethane)](PF₆)₂

Guidance literature:: In 1,2-dichloro-ethane; for 5h; Inert atmosphere; Reflux;
DOI:10.1021/ic302489a

Reference yield:

: ammonium hexafluorophosphate

: cis-bis-(2,2′-bipyridine) dichlororuthenium(II) dihydrate

: 622-20-8
1,2-bis(phenylthio)ethane

: 97278-96-1
[Ru(2,2′-bipyridine)₂(1,2-bis(phenylthio)ethane)](PF₆)₂

Guidance literature:: In ethanol; water; Ru complex and an excess of the thioether are added to aq. ethanol, mixt. is deaerated and heated at reflux with vigorous stirring for 1-4 h, then extd. with Et2O, NH4PF6 is added; ppt. is filtered, washed with water and ether, dried in air, chromd. (alumina, CH3CN/C6H5CH3), pptd. from CH3CN/Et2O or acetone/Et2O; elem. anal.;

Reference yield:

: ammonium hexafluorophosphate

: cis-dichloro(2,2′-bipyridine)ruthenium(II)chloride

: 622-20-8
1,2-bis(phenylthio)ethane

: 97278-96-1
[Ru(2,2′-bipyridine)₂(1,2-bis(phenylthio)ethane)](PF₆)₂

Guidance literature:: In ethylene glycol; ligand was added to soln. of Ru complex in ethylene glycol; heated at 140°C for 4 h; cooled to room temp.; aq. satd. NH4PF6 was added; filtered; washed (cold H2O, ether); dried (vac.); elem. anal.;
DOI:10.1021/ic102482c