trans,trans-3-(6'-bromohexyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane

Base Information

Chemical Name:trans,trans-3-(6'-bromohexyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane
CAS No.:114423-62-0
Molecular Formula:C₂₈H₅₉BrO₂Si₂
Molecular Weight:563.85
Hs Code.:

Synonyms:trans,trans-3-(6'-bromohexyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of trans,trans-3-(6'-bromohexyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane

Chemical Property:

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Technology Process of trans,trans-3-(6'-bromohexyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane

There total 6 articles about trans,trans-3-(6'-bromohexyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 103588-79-0
(1,1,2,2-tetramethyleth-1-yl)-dimethylsilyl trifluoromethanesulfonate

: 114423-61-9
trans,trans-3-(6'-bromohexyl)-1,2-cyclohexanediol

: 114423-62-0
trans,trans-3-(6'-bromohexyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane

Guidance literature:: With lutidine; In dichloromethane; at 0 - 20 ℃;
DOI:10.1021/jo00247a014

Reference yield:

: 4286-55-9
1-bromo-6-hexanol

: 114423-62-0
trans,trans-3-(6'-bromohexyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane

Guidance literature:: Multi-step reaction with 5 steps

1: 95 percent / Et₃N, bis(trimethylsilyl)amine / tetrahydrofuran / Ambient temperature

3: 1.) BH₃*Me₂S, 2.) 3 N NaOH, 30percent H₂O₂ / 1.) THF, RT, 3 days 2.) 1 h

4: 84 percent / CBr₄, PPh₃ / acetonitrile / 1 h / 0 °C

5: 95 percent / lutidine / CH₂Cl₂ / 0 - 20 °C

With sodium hydroxide; carbon tetrabromide; dimethylsulfide borane complex; lutidine; dihydrogen peroxide; triethylamine; triphenylphosphine; 1,1,1,3,3,3-hexamethyl-disilazane; In tetrahydrofuran; dichloromethane; acetonitrile;
DOI:10.1021/jo00247a014

Reference yield:

: 4224-70-8
6-bromohexanoic acid

: 114423-62-0
trans,trans-3-(6'-bromohexyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane

Guidance literature:: Multi-step reaction with 6 steps

1: 98 percent / BH₃*Me₂S / tetrahydrofuran / 0 °C

2: 95 percent / Et₃N, bis(trimethylsilyl)amine / tetrahydrofuran / Ambient temperature

4: 1.) BH₃*Me₂S, 2.) 3 N NaOH, 30percent H₂O₂ / 1.) THF, RT, 3 days 2.) 1 h

5: 84 percent / CBr₄, PPh₃ / acetonitrile / 1 h / 0 °C

6: 95 percent / lutidine / CH₂Cl₂ / 0 - 20 °C

With sodium hydroxide; carbon tetrabromide; dimethylsulfide borane complex; lutidine; dihydrogen peroxide; triethylamine; triphenylphosphine; 1,1,1,3,3,3-hexamethyl-disilazane; In tetrahydrofuran; dichloromethane; acetonitrile;
DOI:10.1021/jo00247a014