(C₅Me₅)Ir(2-(2-trifluoromethylanilino-4,6-di-tert-butylphenol^(2-))

Base Information

• Chemical Name: (C₅Me₅)Ir(2-(2-trifluoromethylanilino-4,6-di-tert-butylphenol^(2-))
• CAS No.: 1008364-25-7
• Molecular Formula: C₃₁H₃₉F₃IrNO
• Molecular Weight: 690.872
• Mol file: 1008364-25-7.mol

Synonyms:(C₅Me₅)Ir(2-(2-trifluoromethylanilino-4,6-di-tert-butylphenol^(2-))

Chemical Property of (C₅Me₅)Ir(2-(2-trifluoromethylanilino-4,6-di-tert-butylphenol^(2-))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₅Me₅)Ir(2-(2-trifluoromethylanilino-4,6-di-tert-butylphenol^(2-))

There total 2 articles about (C₅Me₅)Ir(2-(2-trifluoromethylanilino-4,6-di-tert-butylphenol^(2-)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[(C5Me5)Ir(2-(2-trifluoromethylanilino-4,6-di-tert-butylphenol(2-))]PF6 → (C5Me5)Ir(2-(2-trifluoromethylanilino-4,6-di-tert-butylphenol(2-)) (1008364-25-7)

Guidance literature:

With H₂; In dichloromethane;

DOI:10.1021/ja076801k

Reference yield:

2-(2-trifluoromethyl)anilino-4,6-di-tert-butylphenol (845726-51-4) + bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] (12354-84-6,12354-85-7) → (C5Me5)Ir(2-(2-trifluoromethylanilino-4,6-di-tert-butylphenol(2-)) (1008364-25-7)

Guidance literature:

With base; In not given;

DOI:10.1021/ja076801k

Reference yield: 42.0%

(C5Me5)Ir(2-(2-trifluoromethylanilino-4,6-di-tert-butylphenol(2-)) (1008364-25-7) + silver trifluoromethanesulfonate (2923-28-6) + acetonitrile (75-05-8,26809-02-9) → [Cp(*)Ir(2-(2-trifluoromethyl)amino-4,6-di-tert-butylphenol(-2H))(acetonitrile)](OTf)2

Guidance literature:

In dichloromethane; acetonitrile; (Schlenk technique); Ag salt in CH2Cl2 added to a soln. of Ir complex inCH2Cl2 with MeCN, stirred at room temp. for 5 h; concd., overlayed with Et2O, filtered, crystd. (CH2Cl2/Et2O, at -30°C);

DOI:10.1021/om9010593

upstream raw materials:

2-(2-trifluoromethyl)anilino-4,6-di-tert-butylphenol

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]