2-allyl-6-methoxy-4-methylphenyl trifluoromethanesulfonate

Base Information

• Chemical Name: 2-allyl-6-methoxy-4-methylphenyl trifluoromethanesulfonate
• CAS No.: 1256811-75-2
• Molecular Formula: C₁₂H₁₃F₃O₄S
• Molecular Weight: 310.294
• Mol file: 1256811-75-2.mol

Synonyms:2-allyl-6-methoxy-4-methylphenyl trifluoromethanesulfonate

Chemical Property of 2-allyl-6-methoxy-4-methylphenyl trifluoromethanesulfonate

Chemical Property:

Purity/Quality:

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Technology Process of 2-allyl-6-methoxy-4-methylphenyl trifluoromethanesulfonate

There total 1 articles about 2-allyl-6-methoxy-4-methylphenyl trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

N,N-phenylbistrifluoromethane-sulfonimide (37595-74-7) + 2-allyl-4-methyl-6-methoxyphenol (77879-82-4) → 2-allyl-6-methoxy-4-methylphenyl trifluoromethanesulfonate (1256811-75-2)

Guidance literature:

With caesium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 18h; Inert atmosphere;

DOI:10.1021/jo1018377

Reference yield: 89.0%

2-allyl-6-methoxy-4-methylphenyl trifluoromethanesulfonate (1256811-75-2) + potassium trifluoro(2-trimethylsilylethynyl)boranuide → ((2-allyl-6-methoxy-4-methylphenyl)ethynyl)trimethylsilane (1256811-77-4)

Guidance literature:

With potassium phosphate; palladium diacetate; ruphos; In tetrahydrofuran; water; for 4h; Reflux; Inert atmosphere;

DOI:10.1021/jo1018377

upstream raw materials:

N,N-phenylbistrifluoromethane-sulfonimide

2-allyl-4-methyl-6-methoxyphenol

Downstream raw materials:

((2-allyl-6-methoxy-4-methylphenyl)ethynyl)trimethylsilane