Ethiprole

Base Information

Chemical Name:Ethiprole
CAS No.:181587-01-9
Molecular Formula:C13H9Cl2F3N4OS
Molecular Weight:397.208
Hs Code.:
European Community (EC) Number:446-630-3,605-936-9
UNII:5527E53JNB
DSSTox Substance ID:DTXSID6058003
Nikkaji Number:J1.979.586A
Wikidata:Q22807466
ChEMBL ID:CHEMBL2228921
Mol file:181587-01-9.mol

Synonyms:ethiprole

Suppliers and Price of Ethiprole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Ethiprole
5g
$ 215.00

Sigma-Aldrich
Ethiprole PESTANAL?, analytical standard
100 mg
$ 54.30

Sigma-Aldrich
Ethiprole PESTANAL?, analytical standard
100mg-r
$ 52.60

Medical Isotopes, Inc.
Ethiprole
250 mg
$ 620.00

Chemenu
5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-ethylsulfinylpyrazole-3-carbonitrile 95%+
100mg
$ 56.00

AK Scientific
Ethiprole
5g
$ 600.00

AK Scientific
Ethiprole
100mg
$ 42.00

Total 65 raw suppliers

Chemical Property of Ethiprole

Chemical Property:

Appearance/Colour:white powder
Vapor Pressure:0mmHg at 25°C
Melting Point:~174°
Refractive Index:1.655
Boiling Point:563.464 °C at 760 mmHg
PKA:-3.91±0.20(Predicted)
Flash Point:294.572 °C
PSA：103.91000
Density:1.691 g/cm³
LogP:5.22618
Storage Temp.:0-6°C
Water Solubility.:9.2mg/L at 20℃
XLogP3:3.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:8
Rotatable Bond Count:3
Exact Mass:395.9826220
Heavy Atom Count:24
Complexity:531

Purity/Quality:

99.9% ^*data from raw suppliers

Ethiprole ^*data from reagent suppliers

Safty Information:

Pictogram(s): T, N
Hazard Codes:T,N,Xn
Statements: 23/24/25-48/25-50/53-48/22
Safety Statements: 36/37-45-60-61

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCS(=O)C1=C(N(N=C1C#N)C2=C(C=C(C=C2Cl)C(F)(F)F)Cl)N
Uses Ethiprole is a phenylpyrazole based insecticide used in rice ecosystem on Trichogramma japonicum, and egg parasitoid of rice lepidopterans. Insecticide for chewing and sucking insects.

Technology Process of Ethiprole

There total 3 articles about Ethiprole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 120068-56-6
5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-ethylthio-1H-pyrazole-3-carbonitrile

: 181587-01-9
ethiprole

Guidance literature:: With dihydrogen peroxide; trifluoroacetic acid; In dichloromethane; at 10 - 12 ℃; for 4h;
DOI:10.1016/j.jfluchem.2006.04.002

Reference yield:

: 130755-46-3
4,4'-dithiobis [5-amino-3-cyano-1-{2,6-dichloro-4-(trifluoromethyl)phenyl}-1H-pyrazole]

: 181587-01-9
ethiprole

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / Na₂S₂O₄; Na₂HPO₄ / dimethylformamide; H₂O / 1 h / 20 °C

2: 95 percent / CF₃COOH; aq. H₂O₂ / CH₂Cl₂ / 4 h / 10 - 12 °C

With disodium hydrogenphosphate; sodium dithionite; dihydrogen peroxide; trifluoroacetic acid; In dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1016/j.jfluchem.2006.04.002