1-(4,6-O-benzylidene-2,3-dideoxy-3-hydroxylamino-β-D-arabino-hexopyranosyl)uracil

Base Information

Chemical Name:1-(4,6-O-benzylidene-2,3-dideoxy-3-hydroxylamino-β-D-arabino-hexopyranosyl)uracil
CAS No.:176755-78-5
Molecular Formula:C₁₇H₁₉N₃O₆
Molecular Weight:361.354
Hs Code.:

Synonyms:1-(4,6-O-benzylidene-2,3-dideoxy-3-hydroxylamino-β-D-arabino-hexopyranosyl)uracil

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Chemical Property of 1-(4,6-O-benzylidene-2,3-dideoxy-3-hydroxylamino-β-D-arabino-hexopyranosyl)uracil

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Technology Process of 1-(4,6-O-benzylidene-2,3-dideoxy-3-hydroxylamino-β-D-arabino-hexopyranosyl)uracil

There total 4 articles about 1-(4,6-O-benzylidene-2,3-dideoxy-3-hydroxylamino-β-D-arabino-hexopyranosyl)uracil which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 176895-46-8
1-(4,6-O-benzylidene-2,3-dideoxy-3-nitro-β-D-arabino-hexopyranosyl)uracil

: 176755-78-5
1-(4,6-O-benzylidene-2,3-dideoxy-3-hydroxylamino-β-D-arabino-hexopyranosyl)uracil

: 1-((2R,4aR,6R,8R,8aS)-8-Nitroso-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-1H-pyrimidine-2,4-dione

Guidance literature:: With zinc; In ethanol; acetic acid; for 0.5h; Ambient temperature;
DOI:10.1080/07328319608002131

Reference yield:

: 100-52-7
benzaldehyde

: 176755-78-5
1-(4,6-O-benzylidene-2,3-dideoxy-3-hydroxylamino-β-D-arabino-hexopyranosyl)uracil

Guidance literature:: Multi-step reaction with 3 steps

1: 69 percent / ZnCl₂ / 24 h / Ambient temperature

2: 1) pyridine, Ac₂O, 2.) NaBH₄ / 1.) rt, 40 min, 2.) DMF, rt, 2 h

3: 73 percent / Zn / ethanol; acetic acid / 0.5 h / Ambient temperature

With pyridine; sodium tetrahydroborate; acetic anhydride; zinc(II) chloride; zinc; In ethanol; acetic acid;
DOI:10.1080/07328319608002131

Reference yield:

: 1-((2R,3R,4S,6R)-3,5-Dihydroxy-6-hydroxymethyl-4-nitro-tetrahydro-pyran-2-yl)-1H-pyrimidine-2,4-dione

: 176755-78-5
1-(4,6-O-benzylidene-2,3-dideoxy-3-hydroxylamino-β-D-arabino-hexopyranosyl)uracil

Guidance literature:: Multi-step reaction with 3 steps

1: 69 percent / ZnCl₂ / 24 h / Ambient temperature

2: 1) pyridine, Ac₂O, 2.) NaBH₄ / 1.) rt, 40 min, 2.) DMF, rt, 2 h

3: 73 percent / Zn / ethanol; acetic acid / 0.5 h / Ambient temperature

With pyridine; sodium tetrahydroborate; acetic anhydride; zinc(II) chloride; zinc; In ethanol; acetic acid;
DOI:10.1080/07328319608002131