(E)-(4R,5R)-5-Benzyl-1-(tert-butyl-dimethyl-silanyloxy)-undec-6-en-4-ol

Base Information

Chemical Name:(E)-(4R,5R)-5-Benzyl-1-(tert-butyl-dimethyl-silanyloxy)-undec-6-en-4-ol
CAS No.:162020-89-5
Molecular Formula:C₂₄H₄₂O₂Si
Molecular Weight:390.682
Hs Code.:

Synonyms:(E)-(4R,5R)-5-Benzyl-1-(tert-butyl-dimethyl-silanyloxy)-undec-6-en-4-ol

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Chemical Property of (E)-(4R,5R)-5-Benzyl-1-(tert-butyl-dimethyl-silanyloxy)-undec-6-en-4-ol

Chemical Property:

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Technology Process of (E)-(4R,5R)-5-Benzyl-1-(tert-butyl-dimethyl-silanyloxy)-undec-6-en-4-ol

There total 8 articles about (E)-(4R,5R)-5-Benzyl-1-(tert-butyl-dimethyl-silanyloxy)-undec-6-en-4-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 162020-80-6
{(E)-(R)-2-[(R)-4-(tert-Butyl-dimethyl-silanyloxy)-1-trimethylsilanyloxy-butyl]-oct-3-enyl}-benzene

: 162020-89-5
(E)-(4R,5R)-5-Benzyl-1-(tert-butyl-dimethyl-silanyloxy)-undec-6-en-4-ol

Guidance literature:: With hydrogenchloride; In water; ethyl acetate;
DOI:10.1016/0040-4039(94)02416-9

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 162020-89-5
(E)-(4R,5R)-5-Benzyl-1-(tert-butyl-dimethyl-silanyloxy)-undec-6-en-4-ol

Guidance literature:: Multi-step reaction with 8 steps

1: 2,6-lutidine

2: O₃, dimethyl sulfide

3: 75 percent / Bu₂BOTf, iPr₂NEt

4: 97 percent / AlMe₃

5: 90 percent / Et₃N

6: 73 percent / DIBAL / tetrahydrofuran / 0 °C

7: 35 percent / CrCl₂ / dimethylformamide

8: 86 percent / 0.5M HCl / H₂O; ethyl acetate

With 2,6-dimethylpyridine; chromium dichloride; hydrogenchloride; dimethylsulfide; di-n-butylboryl trifluoromethanesulfonate; trimethylaluminum; diisobutylaluminium hydride; ozone; triethylamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; water; ethyl acetate; N,N-dimethyl-formamide;
DOI:10.1016/0040-4039(94)02416-9

Reference yield:

: 87184-81-4
4-(tert-butyldimethylsilanyloxy)butanal

: 162020-89-5
(E)-(4R,5R)-5-Benzyl-1-(tert-butyl-dimethyl-silanyloxy)-undec-6-en-4-ol

Guidance literature:: Multi-step reaction with 6 steps

1: 75 percent / Bu₂BOTf, iPr₂NEt

2: 97 percent / AlMe₃

3: 90 percent / Et₃N

4: 73 percent / DIBAL / tetrahydrofuran / 0 °C

5: 35 percent / CrCl₂ / dimethylformamide

6: 86 percent / 0.5M HCl / H₂O; ethyl acetate

With chromium dichloride; hydrogenchloride; di-n-butylboryl trifluoromethanesulfonate; trimethylaluminum; diisobutylaluminium hydride; triethylamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; water; ethyl acetate; N,N-dimethyl-formamide;
DOI:10.1016/0040-4039(94)02416-9