{(E)-(R)-2-[(R)-4-(tert-Butyl-dimethyl-silanyloxy)-1-trimethylsilanyloxy-butyl]-oct-3-enyl}-benzene

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Chemical Name:{(E)-(R)-2-[(R)-4-(tert-Butyl-dimethyl-silanyloxy)-1-trimethylsilanyloxy-butyl]-oct-3-enyl}-benzene
CAS No.:162020-80-6
Molecular Formula:C₂₇H₅₀O₂Si₂
Molecular Weight:462.864
Hs Code.:

Synonyms:{(E)-(R)-2-[(R)-4-(tert-Butyl-dimethyl-silanyloxy)-1-trimethylsilanyloxy-butyl]-oct-3-enyl}-benzene

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Chemical Property of {(E)-(R)-2-[(R)-4-(tert-Butyl-dimethyl-silanyloxy)-1-trimethylsilanyloxy-butyl]-oct-3-enyl}-benzene

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Technology Process of {(E)-(R)-2-[(R)-4-(tert-Butyl-dimethyl-silanyloxy)-1-trimethylsilanyloxy-butyl]-oct-3-enyl}-benzene

There total 8 articles about {(E)-(R)-2-[(R)-4-(tert-Butyl-dimethyl-silanyloxy)-1-trimethylsilanyloxy-butyl]-oct-3-enyl}-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 162020-79-3
(2S,3R)-2-Benzyl-6-(tert-butyl-dimethyl-silanyloxy)-3-trimethylsilanyloxy-hexanal

: Dipentyl-diphenyl-phosphonium; iodide

: 162020-80-6
{(E)-(R)-2-[(R)-4-(tert-Butyl-dimethyl-silanyloxy)-1-trimethylsilanyloxy-butyl]-oct-3-enyl}-benzene

Guidance literature:: With sodium amide; In tetrahydrofuran; Heating;
DOI:10.1016/0040-4039(94)02416-9

Reference yield: 35.0%

: 66688-35-5
1,1-diiodopentane

: 162020-79-3
(2S,3R)-2-Benzyl-6-(tert-butyl-dimethyl-silanyloxy)-3-trimethylsilanyloxy-hexanal

: 162020-80-6
{(E)-(R)-2-[(R)-4-(tert-Butyl-dimethyl-silanyloxy)-1-trimethylsilanyloxy-butyl]-oct-3-enyl}-benzene

Guidance literature:: With chromium dichloride; In N,N-dimethyl-formamide;
DOI:10.1016/0040-4039(94)02416-9

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 162020-80-6
{(E)-(R)-2-[(R)-4-(tert-Butyl-dimethyl-silanyloxy)-1-trimethylsilanyloxy-butyl]-oct-3-enyl}-benzene

Guidance literature:: Multi-step reaction with 7 steps

1: 2,6-lutidine

2: O₃, dimethyl sulfide

3: 75 percent / Bu₂BOTf, iPr₂NEt

4: 97 percent / AlMe₃

5: 90 percent / Et₃N

6: 73 percent / DIBAL / tetrahydrofuran / 0 °C

7: 35 percent / CrCl₂ / dimethylformamide

With 2,6-dimethylpyridine; chromium dichloride; dimethylsulfide; di-n-butylboryl trifluoromethanesulfonate; trimethylaluminum; diisobutylaluminium hydride; ozone; triethylamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1016/0040-4039(94)02416-9