Technology Process of C41H62O7S
There total 9 articles about C41H62O7S which
guide to synthetic route it.
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synthetic route:
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128292-38-6
(3S,8S,9S,10R,13S,14S,16R,17R)-17-((1S,2R)-2-Hydroxy-1,5-dimethyl-hexyl)-10,13-dimethyl-3-(tetrahydro-pyran-2-yloxy)-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-16-ol
- Guidance literature:
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With
pyridine; dmap;
In
dichloromethane;
at 0 ℃;
for 72h;
- Guidance literature:
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Multi-step reaction with 8 steps
1: 96 percent / (PhMe2Si)2CuLi*LiCN / tetrahydrofuran / 0.5 h / 0 °C
3: ICl / CH2Cl2 / 2 h / Heating
4: 98 percent / Et3N / CHCl3 / 3 h / 0 deg C -> RT
5: (n-Bu)3SnH, AIBN / benzene / 12 h / Heating
6: 65 percent / KOH, DMSO / 16 h / 60 °C
7: 75 percent / KHCO3, 70percent aq. H2O2 / tetrahydrofuran; methanol / Heating
8: 88 percent / pyridine, DMAP / CH2Cl2 / 72 h / 0 °C
With
pyridine; dmap; potassium hydroxide; 2,2'-azobis(isobutyronitrile); dihydrogen peroxide; tri-n-butyl-tin hydride; Iodine monochloride; potassium hydrogencarbonate; (PhMe2Si)2CuLi*LiCN; dimethyl sulfoxide; triethylamine;
In
tetrahydrofuran; methanol; dichloromethane; chloroform; benzene;
- Guidance literature:
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Multi-step reaction with 5 steps
1: 98 percent / Et3N / CHCl3 / 3 h / 0 deg C -> RT
2: (n-Bu)3SnH, AIBN / benzene / 12 h / Heating
3: 65 percent / KOH, DMSO / 16 h / 60 °C
4: 75 percent / KHCO3, 70percent aq. H2O2 / tetrahydrofuran; methanol / Heating
5: 88 percent / pyridine, DMAP / CH2Cl2 / 72 h / 0 °C
With
pyridine; dmap; potassium hydroxide; 2,2'-azobis(isobutyronitrile); dihydrogen peroxide; tri-n-butyl-tin hydride; potassium hydrogencarbonate; dimethyl sulfoxide; triethylamine;
In
tetrahydrofuran; methanol; dichloromethane; chloroform; benzene;