2-(trimethylsilyl)ethyl (4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)-[(4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)]₂-4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranoside

Base Information

• Chemical Name: 2-(trimethylsilyl)ethyl (4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)-[(4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)]₂-4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranoside
• CAS No.: 172471-72-6
• Molecular Formula: C₅₇H₇₄N₁₂O₁₃Si
• Molecular Weight: 1163.37

Synonyms:2-(trimethylsilyl)ethyl (4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)-[(4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)]₂-4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranoside

Chemical Property of 2-(trimethylsilyl)ethyl (4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)-[(4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)]₂-4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(trimethylsilyl)ethyl (4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)-[(4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)]₂-4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranoside

There total 4 articles about 2-(trimethylsilyl)ethyl (4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)-[(4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)]₂-4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-(trimethylsilyl)ethyl (2-O-acetyl-4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)-(4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)-(4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)-4-azido-3-O-benzyl-4,6-dideox... → 2-(trimethylsilyl)ethyl (4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)-[(4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)]2-4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranoside (172471-72-6)

Guidance literature:

With sodium methylate; In methanol;

DOI:10.1016/0008-6215(96)00202-9

Reference yield:

2-O-(2-O-acetyl-4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl chloride (172471-70-4) → 2-(trimethylsilyl)ethyl (4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)-[(4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)]2-4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranoside (172471-72-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 83 percent / AgOTf, 2,6-di-tert-butyl-4-methylpyridine / CH₂Cl₂ / 1 h

2: NaOMe / methanol

With 2,6-di-tert-butyl-4-methylpyridine; sodium methylate; silver trifluoromethanesulfonate; In methanol; dichloromethane;

DOI:10.1016/0008-6215(96)00202-9

Reference yield:

Acetic acid (2R,3S,4S,5R,6R)-5-azido-2-[(2S,3S,4S,5R,6R)-5-azido-4-benzyloxy-6-methyl-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yloxy]-4-benzyloxy-6-methyl-tetrahydro-pyran-3-yl ester (172471-69-1) → 2-(trimethylsilyl)ethyl (4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)-[(4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)]2-4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranoside (172471-72-6)

Guidance literature:

Multi-step reaction with 3 steps

1: 81 percent / dichloromethyl methyl ether, ZnCl₂ / CH₂Cl₂ / 3 h / Ambient temperature

2: 83 percent / AgOTf, 2,6-di-tert-butyl-4-methylpyridine / CH₂Cl₂ / 1 h

3: NaOMe / methanol

With 2,6-di-tert-butyl-4-methylpyridine; Dichloromethyl methyl ether; sodium methylate; silver trifluoromethanesulfonate; zinc(II) chloride; In methanol; dichloromethane;

DOI:10.1016/0008-6215(96)00202-9

upstream raw materials:

2-O-(2-O-acetyl-4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl chloride

2-(trimethylsilyl)ethyl 4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl-(1→2)-4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranoside

Acetic acid (2R,3S,4S,5R,6R)-5-azido-2-[(2S,3S,4S,5R,6R)-5-azido-4-benzyloxy-6-methyl-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yloxy]-4-benzyloxy-6-methyl-tetrahydro-pyran-3-yl ester

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 172471-72-6 2-(trimethylsilyl)ethyl (4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)-[(4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranosyl)-(1-> 2)]₂-4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranoside

Send

Send

Metric Ton KG G Pound L ML

Send

Send