Brosylate Ester of anti-3-(Hydroxymethyl)-6-oxabicyclo<3.1.0>hexane

Base Information

Chemical Name:Brosylate Ester of anti-3-(Hydroxymethyl)-6-oxabicyclo<3.1.0>hexane
CAS No.:72598-08-4
Molecular Formula:C₁₂H₁₃BrO₄S
Molecular Weight:333.203
Hs Code.:

Synonyms:Brosylate Ester of anti-3-(Hydroxymethyl)-6-oxabicyclo<3.1.0>hexane

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Chemical Property of Brosylate Ester of anti-3-(Hydroxymethyl)-6-oxabicyclo<3.1.0>hexane

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Technology Process of Brosylate Ester of anti-3-(Hydroxymethyl)-6-oxabicyclo<3.1.0>hexane

There total 2 articles about Brosylate Ester of anti-3-(Hydroxymethyl)-6-oxabicyclo<3.1.0>hexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 25125-21-7
4-(hydroxymethyl)cyclopentene

: 72598-08-4
Brosylate Ester of anti-3-(Hydroxymethyl)-6-oxabicyclo<3.1.0>hexane

Guidance literature:: Multi-step reaction with 2 steps

1: m-chloroperbenzoic acid (85percent) / CH₂Cl₂ / 1.) 0 deg C, 1 h, 2.) room temperature, 3 h

2: pyridine

With 3-chloro-benzenecarboperoxoic acid; In pyridine; dichloromethane;
DOI:10.1021/jo00330a027

Reference yield:

: 72656-82-7
anti-3-(Hydroxymethyl)-6-oxabicyclo<3.1.0>hexane

: 98-58-8
4-bromobenzenesulfonyl chloride

: 72598-08-4
Brosylate Ester of anti-3-(Hydroxymethyl)-6-oxabicyclo<3.1.0>hexane

Guidance literature:: In pyridine; Yield given;
DOI:10.1021/jo00330a027

Reference yield:

: 72598-08-4
Brosylate Ester of anti-3-(Hydroxymethyl)-6-oxabicyclo<3.1.0>hexane

: 36368-48-6
exo-2-Oxabicyclo<2.2.1>hept-6-yl Brosylate

Guidance literature:: Multi-step reaction with 3 steps

1: 53 percent Chromat_. / CaCO₃, H₂O / ethanol; H₂O / 65 h / 70 - 75 °C

2: 40 percent / 0.42 N butyllithium / diethyl ether; tetrahydrofuran / 69 h / Heating

3: pyridine / 1.) 5 deg C, 2.) refrigerator

With n-butyllithium; water; calcium carbonate; In tetrahydrofuran; pyridine; diethyl ether; ethanol; water;
DOI:10.1021/jo00330a027