trans-[2-(hydroxymethyl)phenyl]iodobis(triphenylphosphine)palladium

Base Information

• Chemical Name: trans-[2-(hydroxymethyl)phenyl]iodobis(triphenylphosphine)palladium
• CAS No.: 353798-13-7
• Molecular Formula: C₄₃H₃₇IOP₂Pd
• Molecular Weight: 865.038
• Mol file: 353798-13-7.mol

Synonyms:trans-[2-(hydroxymethyl)phenyl]iodobis(triphenylphosphine)palladium

Chemical Property of trans-[2-(hydroxymethyl)phenyl]iodobis(triphenylphosphine)palladium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of trans-[2-(hydroxymethyl)phenyl]iodobis(triphenylphosphine)palladium

There total 2 articles about trans-[2-(hydroxymethyl)phenyl]iodobis(triphenylphosphine)palladium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

tetrakis(triphenylphosphine) palladium(0) (14221-01-3) + 2-iodobenzyl alcohol (5159-41-1) → trans-[2-(hydroxymethyl)phenyl]iodobis(triphenylphosphine)palladium (353798-13-7)

Guidance literature:

In toluene; Sonication; (Ar); addn. of palladium complex to a soln. of ligand in toluene, brief sonication, heating to 40°C for 3 h; filtration, washing with Et2O, recrystn. (THF/Et2O); elem. anal.;

DOI:10.1021/om0010565

Reference yield: 56.8%

2-iodobenzyl alcohol (5159-41-1) + triphenylphosphine (603-35-0) + bis(dibenzylideneacetone)-palladium(0) (32005-36-0) → trans-[2-(hydroxymethyl)phenyl]iodobis(triphenylphosphine)palladium (353798-13-7)

Guidance literature:

In toluene; at 20 ℃; for 0.25h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.organomet.5b00309

Reference yield: 98.0%

1,1'-bis-(diphenylphosphino)ferrocene (12150-46-8) + trans-[2-(hydroxymethyl)phenyl]iodobis(triphenylphosphine)palladium (353798-13-7) → [2-(hydroxymethyl)phenyl]iodo[1,1'-bis(diphenylphosphino)ferrocene]palladium (353798-14-8)

Guidance literature:

In dichloromethane; (Ar); addn. of iron complex to a soln. of palladium complex in CH2Cl2 at23°C for 1 h; evapn., trituration with Et2O;

DOI:10.1021/om0010565

upstream raw materials:

tetrakis(triphenylphosphine) palladium⁽⁰⁾

2-iodobenzyl alcohol

triphenylphosphine

bis(dibenzylideneacetone)-palladium⁽⁰⁾

Downstream raw materials:

[2-(hydroxymethyl)phenyl]iodo[1,1'-bis(diphenylphosphino)ferrocene]palladium