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1,1'-Bis(diphenylphosphino)ferrocene Manufacturer/High quality/Best price/In stock
Cas No: 12150-46-8
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Hangzhou Dayangchem Co., Ltd. Contact Supplier
1,1'-Bis(diphenylphosphino)ferrocene
Cas No: 12150-46-8
No Data No Data Metric Ton/Day Beijing Greenchem Technology Co.,Ltd.(Qingdao Greenchem international Trading Co.,Ltd) Contact Supplier
1,1'-Bis(diphenylphosphino)ferrocene 12150-46-8
Cas No: 12150-46-8
No Data 10 Kilogram 10 Kilogram/Day Zouping Mingxing Chemical Co.,Ltd. Contact Supplier
1,1'-Bis(diphenylphosphino)ferrocene
Cas No: 12150-46-8
No Data 100 Gram 500 Kilogram/Month Puyang Huicheng Electronic Material Co., Ltd Contact Supplier
1,1'-Bis(diphenylphosphino)ferrocene
Cas No: 12150-46-8
USD $ 1.0-2.0 / Metric Ton 1 Metric Ton 500 Metric Ton/Week Hebei yanxi chemical co.,LTD. Contact Supplier
High quality 1,1-Bis(diphenylphosphino)ferrocene Cas 12150-46-8 with favorable price
Cas No: 12150-46-8
USD $ 295.0-300.0 / Kilogram 1 Kilogram 10 Metric Ton/Year Wuhan Fortuna Chemical Co.,Ltd Contact Supplier
1,1'-Bis(diphenylphosphino)ferrocene
Cas No: 12150-46-8
No Data 1 Kilogram 20 Metric Ton/Month Henan Allgreen Chemical Co.,Ltd Contact Supplier
High quality 1,1'-Bis(Diphenylphosphino)Ferrocene supplier in China
Cas No: 12150-46-8
No Data No Data No Data Simagchem Corporation Contact Supplier
1,1'-Bis(diphenylphosphino)ferrocene
Cas No: 12150-46-8
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
1,1'-Bis-(diphenylphosphino)-ferrocene
Cas No: 12150-46-8
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier

12150-46-8 Usage

Uses

suzuki reaction

Reaction

  1. Ligand for Pd-catalyzed cross-coupling.
  2. Useful ligand for Pd-catalyzed carbon-nitrogen and carbon-oxygen bond forming procedures.
  3. Ligand for Ni-catalyzed amination of aryl chlorides.
  4. Ligand for Pd-catalyzed conversion of aryl halides to aryl nitriles.
  5. Ligand for Ni-catalyzed Suzuki reactions.
  6. Ni-catalyzed hydroamination of 1,3-dienes.
  7. Pd-catalyzed hydrocarbonation and hydroamination of 3,3-dihexylcyclopropene.
  8. Pd-catalyzed γ-arylation of β,γ-unsaturated ketones.
  9. Ligand for Ru-catalyzed reduction of nitriles to primary amines.
  10. Ligand for Rh-catalyzed alkyne head-to-tail dimerization.
  11. Ligand for Rh-catalyzed cross-coupling
  12. Ligand for Rh-catalyzed olefin isomerization
  13. Ligand for Ni or Rh-catalyzed borylation
  14. Ligand for regioselective Pd-catalyzed hydrophosphinylation of terminal alkynes to form branched alkenes.


Chemical Properties

deep yellow crystalline powder

Uses

Commonly used coordination compound in synthesis, readily forms complexes with various metals, i.e. when reacting with the acetonitrile or benzonitrile complexes of PdCl2 it forms (dppf)PdCl2, which i s a popular reagent for palladium-catalyzed coupling reactions.

Purification Methods

Wash it with distilled H2O and dry it in a vacuum. Dissolve it in ca 5 parts of hot dioxane and cool to give orange crystals m 181-183o. Recrystallisation from *C6H6/heptane (1:2) gives a product with m 183-184o. [Bishop et al. J Organomet Chem 27 241 1971.]

12150-46-8 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Sigma-Aldrich (68646)  ZirconiumionophoreI  Selectophore, function tested 12150-46-8 68646-50MG 705.51CNY Detail
Aldrich (177261)  DPPF  97% 12150-46-8 177261-25G 1,035.10CNY Detail
Aldrich (177261)  DPPF  97% 12150-46-8 177261-10G 549.90CNY Detail
Aldrich (177261)  DPPF  97% 12150-46-8 177261-1G 105.30CNY Detail
Alfa Aesar (B21166)  1,1'-Bis(diphenylphosphino)ferrocene, 97%    12150-46-8 25g 3256.0CNY Detail
Alfa Aesar (B21166)  1,1'-Bis(diphenylphosphino)ferrocene, 97%    12150-46-8 5g 693.0CNY Detail
Alfa Aesar (B21166)  1,1'-Bis(diphenylphosphino)ferrocene, 97%    12150-46-8 1g 235.0CNY Detail
TCI America (B2027)  1,1'-Bis(diphenylphosphino)ferrocene  >96.0%(T) 12150-46-8 25g 980.00CNY Detail
TCI America (B2027)  1,1'-Bis(diphenylphosphino)ferrocene  >96.0%(T) 12150-46-8 5g 280.00CNY Detail
TCI America (B2027)  1,1'-Bis(diphenylphosphino)ferrocene  >96.0%(T) 12150-46-8 1g 80.00CNY Detail

12150-46-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,1'-Bis(diphenylphosphino)ferrocene

1.2 Other means of identification

Product number -
Other names 1'-Bis(diphenylphosphino)ferrocene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:12150-46-8 SDS

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