ethyl (2Z,5R,6Z,8S)-8-{[(tert-butyl)diphenylsilyl]oxy}-5-hydroxydodeca-2,6-dienoate

Base Information

Chemical Name:ethyl (2Z,5R,6Z,8S)-8-{[(tert-butyl)diphenylsilyl]oxy}-5-hydroxydodeca-2,6-dienoate
CAS No.:1401904-95-7
Molecular Formula:C₃₀H₄₂O₄Si
Molecular Weight:494.747
Hs Code.:

Synonyms:ethyl (2Z,5R,6Z,8S)-8-{[(tert-butyl)diphenylsilyl]oxy}-5-hydroxydodeca-2,6-dienoate

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Chemical Property of ethyl (2Z,5R,6Z,8S)-8-{[(tert-butyl)diphenylsilyl]oxy}-5-hydroxydodeca-2,6-dienoate

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Technology Process of ethyl (2Z,5R,6Z,8S)-8-{[(tert-butyl)diphenylsilyl]oxy}-5-hydroxydodeca-2,6-dienoate

There total 10 articles about ethyl (2Z,5R,6Z,8S)-8-{[(tert-butyl)diphenylsilyl]oxy}-5-hydroxydodeca-2,6-dienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 1401904-92-4
ethyl (5R,6Z,8S)-8-{[(tert-Butyl)diphenylsilyl]oxy}-5-hydroxydodec-6-en-2-ynoate

: 1401904-95-7
ethyl (2Z,5R,6Z,8S)-8-{[(tert-butyl)diphenylsilyl]oxy}-5-hydroxydodeca-2,6-dienoate

Guidance literature:: With hydrogen; In benzene; for 5h;
DOI:10.1002/hlca.201200078

Reference yield:

: 1329675-12-8
(2S,4Z)-4-{[(tert-butyl)diphenylsilyl]oxy}oct-2-enal

: 1401904-95-7
ethyl (2Z,5R,6Z,8S)-8-{[(tert-butyl)diphenylsilyl]oxy}-5-hydroxydodeca-2,6-dienoate

Guidance literature:: Multi-step reaction with 4 steps

1.1: tetra-(n-butyl)ammonium iodide; sodium hydroxide / dichloromethane; water

2.1: (S,S)-(salen)Co(III)(AcO) / 0.08 h / 0 °C

2.2: 72 h / 20 °C

3.1: n-butyllithium / hexane; tetrahydrofuran / 0.25 h

3.2: 0.25 h

3.3: 0.5 h / -78 °C

4.1: hydrogen / benzene / 5 h

With n-butyllithium; (S,S)-(salen)Co(III)(AcO); hydrogen; tetra-(n-butyl)ammonium iodide; sodium hydroxide; In tetrahydrofuran; hexane; dichloromethane; water; benzene;
DOI:10.1002/hlca.201200078

Reference yield:

: 1401904-87-7
(tert-butyl){[(1S,2Z)-1-butyl-3-(oxiran-2-yl)prop-2-en-1-yl]oxy}diphenylsilane

: 1401904-95-7
ethyl (2Z,5R,6Z,8S)-8-{[(tert-butyl)diphenylsilyl]oxy}-5-hydroxydodeca-2,6-dienoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: (S,S)-(salen)Co(III)(AcO) / 0.08 h / 0 °C

1.2: 72 h / 20 °C

2.1: n-butyllithium / hexane; tetrahydrofuran / 0.25 h

2.2: 0.25 h

2.3: 0.5 h / -78 °C

3.1: hydrogen / benzene / 5 h

With n-butyllithium; (S,S)-(salen)Co(III)(AcO); hydrogen; In tetrahydrofuran; hexane; benzene;
DOI:10.1002/hlca.201200078