(tert-butyl){[(1S,2Z)-1-butyl-3-[(2S)-oxiran-2-yl]prop-2-en-1-yl]oxy}diphenylsilane

Base Information

• Chemical Name: (tert-butyl){[(1S,2Z)-1-butyl-3-[(2S)-oxiran-2-yl]prop-2-en-1-yl]oxy}diphenylsilane
• CAS No.: 1401904-89-9
• Molecular Formula: C₂₅H₃₄O₂Si
• Molecular Weight: 394.629
• Mol file: 1401904-89-9.mol

Synonyms:(tert-butyl){[(1S,2Z)-1-butyl-3-[(2S)-oxiran-2-yl]prop-2-en-1-yl]oxy}diphenylsilane

Chemical Property of (tert-butyl){[(1S,2Z)-1-butyl-3-[(2S)-oxiran-2-yl]prop-2-en-1-yl]oxy}diphenylsilane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (tert-butyl){[(1S,2Z)-1-butyl-3-[(2S)-oxiran-2-yl]prop-2-en-1-yl]oxy}diphenylsilane

There total 9 articles about (tert-butyl){[(1S,2Z)-1-butyl-3-[(2S)-oxiran-2-yl]prop-2-en-1-yl]oxy}diphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

(tert-butyl){[(1S,2Z)-1-butyl-3-(oxiran-2-yl)prop-2-en-1-yl]oxy}diphenylsilane (1401904-87-7) → (tert-butyl){[(1S,2Z)-1-butyl-3-[(2S)-oxiran-2-yl]prop-2-en-1-yl]oxy}diphenylsilane (1401904-89-9) + (tert-butyl){[(1S,2Z)-1-butyl-3-[(2S)-oxiran-2-yl]prop-2-en-1-yl]oxy}diphenylsilane

Guidance literature:

(tert-butyl){[(1S,2Z)-1-butyl-3-(oxiran-2-yl)prop-2-en-1-yl]oxy}diphenylsilane; With (S,S)-(salen)Co(III)(AcO); at 0 ℃; for 0.0833333h;

With water; at 20 ℃; for 72h;

DOI:10.1002/hlca.201200078

Reference yield:

(2R,3R)-(3-butyloxiranyl)methyl alcohol (104528-17-8,76639-81-1,84248-80-6,84248-81-7,97275-47-3,138051-65-7,144831-33-4) → (tert-butyl){[(1S,2Z)-1-butyl-3-[(2S)-oxiran-2-yl]prop-2-en-1-yl]oxy}diphenylsilane (1401904-89-9) + (tert-butyl){[(1S,2Z)-1-butyl-3-[(2S)-oxiran-2-yl]prop-2-en-1-yl]oxy}diphenylsilane

Guidance literature:

Multi-step reaction with 7 steps

1.1: triphenylphosphine; sodium hydrogencarbonate / tetrachloromethane / Reflux; Inert atmosphere

2.1: n-butyllithium / hexane; tetrahydrofuran / 0.17 h / -78 °C

3.1: 1H-imidazole / 0 - 20 °C

4.1: n-butyllithium / hexane; tetrahydrofuran / 0.17 h / -78 °C

4.2: 1 h

5.1: hydrogen / dichloromethane

6.1: tetra-(n-butyl)ammonium iodide; sodium hydroxide / dichloromethane; water

7.1: (S,S)-(salen)Co(III)(AcO) / 0.08 h / 0 °C

7.2: 72 h / 20 °C

With 1H-imidazole; n-butyllithium; (S,S)-(salen)Co(III)(AcO); hydrogen; tetra-(n-butyl)ammonium iodide; sodium hydrogencarbonate; triphenylphosphine; sodium hydroxide; In tetrahydrofuran; tetrachloromethane; hexane; dichloromethane; water;

DOI:10.1002/hlca.201200078

Reference yield:

(3R,4R)-1-chloro-3,4-epoxyoctane → (tert-butyl){[(1S,2Z)-1-butyl-3-[(2S)-oxiran-2-yl]prop-2-en-1-yl]oxy}diphenylsilane (1401904-89-9) + (tert-butyl){[(1S,2Z)-1-butyl-3-[(2S)-oxiran-2-yl]prop-2-en-1-yl]oxy}diphenylsilane

Guidance literature:

Multi-step reaction with 6 steps

1.1: n-butyllithium / hexane; tetrahydrofuran / 0.17 h / -78 °C

2.1: 1H-imidazole / 0 - 20 °C

3.1: n-butyllithium / hexane; tetrahydrofuran / 0.17 h / -78 °C

3.2: 1 h

4.1: hydrogen / dichloromethane

5.1: tetra-(n-butyl)ammonium iodide; sodium hydroxide / dichloromethane; water

6.1: (S,S)-(salen)Co(III)(AcO) / 0.08 h / 0 °C

6.2: 72 h / 20 °C

With 1H-imidazole; n-butyllithium; (S,S)-(salen)Co(III)(AcO); hydrogen; tetra-(n-butyl)ammonium iodide; sodium hydroxide; In tetrahydrofuran; hexane; dichloromethane; water;

DOI:10.1002/hlca.201200078

upstream raw materials:

(tert-butyl){[(1S,2Z)-1-butyl-3-(oxiran-2-yl)prop-2-en-1-yl]oxy}diphenylsilane

pentanal

ethyl (E)-2-heptenoate

(E)-hept-2-en-1-ol

Downstream raw materials:

ethyl (2Z,5R,6Z,8S)-8-{[(tert-butyl)diphenylsilyl]oxy}-5-hydroxydodeca-2,6-dienoate

(6R)-6-{(1Z,3S)-3-{[(tert-butyl)diphenylsilyl]oxy}hept-1-en-1-yl}-5,6-dihydro-2H-pyran-2-one

ethyl (5R,6Z,8S)-8-{[(tert-Butyl)diphenylsilyl]oxy}-5-hydroxydodec-6-en-2-ynoate