[phenyltris((tert-butylthio)methyl)borate]CoCl

Base Information

Chemical Name:[phenyltris((tert-butylthio)methyl)borate]CoCl
CAS No.:213008-72-1
Molecular Formula:C₂₁H₃₈BClCoS₃
Molecular Weight:491.988
Hs Code.:

Synonyms:[phenyltris((tert-butylthio)methyl)borate]CoCl

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Chemical Property of [phenyltris((tert-butylthio)methyl)borate]CoCl

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Technology Process of [phenyltris((tert-butylthio)methyl)borate]CoCl

There total 1 articles about [phenyltris((tert-butylthio)methyl)borate]CoCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: cobalt(II) chloride hexahydrate

: 213008-71-0,301663-26-3
thallium phenyltris((tert-butylthio)methyl)borate

: 213008-72-1
[phenyltris((tert-butylthio)methyl)borate]CoCl

Guidance literature:: In dichloromethane; acetone; byproducts: TlCl; addn. of 1 equiv. Tl-complex (in CH2Cl2) to CoCl2 (in Me2CO); recrystn. (CH2Cl2, 0°C); elem. anal.;

Reference yield: 85.0%

: 213008-72-1
[phenyltris((tert-butylthio)methyl)borate]CoCl

: 2999-74-8
dimethylmagnesium

: 326868-92-2
[(phenyltris((tert-butylthio)methyl)borate)Co(Me)]

Guidance literature:: In tetrahydrofuran; treating cobalt complex with freshly prepd. Me2Mg in THF; recrystn. from pentanes;
DOI:10.1021/ja002638g

Reference yield: 71.0%

: 213008-72-1
[phenyltris((tert-butylthio)methyl)borate]CoCl

: 557-18-6
diethylmagnesium

: 929007-44-3
[(phenyltris((tert-butylthio)methyl)borate)Co(Et)]

Guidance literature:: In tetrahydrofuran; 1,4-dioxane; byproducts: MgCl2*C4H8O2; (N2); std. Schlenk technique; Co complex was dissolved in THF; dioxane was added; Mg compd. (2 equiv.) was added dropwise with stirring; stirredat room temp. for 8 h; filtered through Celite; solvent removed in vac. with gentle heating (<=60°C); extd. (pentane); passed through Celite; elem. anal.;
DOI:10.1021/om0608253