Magnesium, diethyl-

Base Information

• Chemical Name: Magnesium, diethyl-
• CAS No.: 557-18-6
• Molecular Formula: C4H10 Mg
• Molecular Weight: 82.4284
• European Community (EC) Number: 209-159-2
• UNII: OE3B0ORY4X
• DSSTox Substance ID: DTXSID9060318
• Mol file: 557-18-6.mol

Synonyms:Diethylmagnesium;MAGNESIUM, DIETHYL-;magnesium diethyl;magnesium;ethane;557-18-6;DIETHYL MAGNESIUM;EINECS 209-159-2;UNII-OE3B0ORY4X;OE3B0ORY4X;C4H10Mg;DIETHYLMAGNESIUM [MI];C4-H10-Mg;DTXSID9060318;HKACPERQNQAGFJ-UHFFFAOYSA-N

Chemical Property of Magnesium, diethyl-

Chemical Property:

• Melting Point: 0°
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 1.68080
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 82.0632920
• Heavy Atom Count: 5
• Complexity: 3.6

Purity/Quality:

99% ^*data from raw suppliers

DIETHYLMAGNESIUM 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[CH2-].C[CH2-].[Mg+2]
• Uses: Diethylmagnesium is used as intermediate inorganic synthesis.

Technology Process of Magnesium, diethyl-

There total 9 articles about Magnesium, diethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

ethyl bromide (74-96-4) → diethylmagnesium (557-18-6)

Guidance literature:

With diethylene glycol dimethyl ether; magnesium; In diethyl ether; at -10 - 0 ℃; for 2h;

DOI:10.1246/cl.1987.2299

Reference yield:

diethylmercury (627-44-1) → diethylmagnesium (557-18-6)

Guidance literature:

With diethyl ether; magnesium;

Reference yield:

ethene (74-85-1) → diethylmagnesium (557-18-6)

Guidance literature:

With magnesium hydride; zirconium(IV) chloride; In tetrahydrofuran; at 75 ℃; for 18h; under 22501.8 Torr; Yield given;

upstream raw materials:

ethylmagnesium bromide

diethylmercury

ethyl bromide

ethene

Downstream raw materials:

butan-1-ol

2-methylpentan-2-ol

2,3-dimethylpentan-2-ol

2,3,3-Trimethyl-2-pentanol

Refernces

THE APPLICATION OF FREE RADICALS TO THE CATALYTIC SYNTHESIS OF CARBON MONOXIDE DERIVATIVES

10.1016/S0022-328X(00)96083-2

The study explores the application of free radicals in the catalytic synthesis of carbon monoxide derivatives, focusing on the reaction of carbon monoxide with organomagnesium compounds in the presence of various carbonyl compounds in tetrahydrofuran. The main product of these reactions was tetrahydrofuranyl-2-ethyl ketone, suggesting a radical mechanism. The reactions were found to be complex, yielding over ten products, including ketones, tertiary alcohols, and hydrocarbons. The study also discusses the potential for other radical sources to facilitate similar reactions, opening new avenues for organic synthesis.

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