(-)-3-<(R)-4-t-Butyldimethylsilyloxy-2,6,6-trimethyl-1-cyclohexen-1-yl>propensaeure

Base Information

Chemical Name:(-)-3-<(R)-4-t-Butyldimethylsilyloxy-2,6,6-trimethyl-1-cyclohexen-1-yl>propensaeure
CAS No.:83021-08-3
Molecular Formula:C₁₈H₃₂O₃Si
Molecular Weight:324.536
Hs Code.:

Synonyms:(-)-3-<(R)-4-t-Butyldimethylsilyloxy-2,6,6-trimethyl-1-cyclohexen-1-yl>propensaeure

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Chemical Property of (-)-3-<(R)-4-t-Butyldimethylsilyloxy-2,6,6-trimethyl-1-cyclohexen-1-yl>propensaeure

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Technology Process of (-)-3-<(R)-4-t-Butyldimethylsilyloxy-2,6,6-trimethyl-1-cyclohexen-1-yl>propensaeure

There total 3 articles about (-)-3-<(R)-4-t-Butyldimethylsilyloxy-2,6,6-trimethyl-1-cyclohexen-1-yl>propensaeure which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 83021-08-3
(-)-3-<(R)-4-t-Butyldimethylsilyloxy-2,6,6-trimethyl-1-cyclohexen-1-yl>propensaeure

Guidance literature:: Multi-step reaction with 2 steps

1: 6.5 g / 4-dimethylaminopyridine, triethylamine / CH₂Cl₂ / 24 h / Ambient temperature

2: 1.) NaOH, Br₂; 2.) Na₂S₂O₅ / 1.) water, dioxane, 1 h, 0 deg C; 2.) water

With dmap; sodium metabisulfite; sodium hydroxide; bromine; triethylamine; In dichloromethane;
DOI:10.1002/hlca.19820650323

Reference yield:

: 50281-38-4
(3R)-3-hydroxy-β-ionone

: 83021-08-3
(-)-3-<(R)-4-t-Butyldimethylsilyloxy-2,6,6-trimethyl-1-cyclohexen-1-yl>propensaeure

Guidance literature:: Multi-step reaction with 2 steps

1: 6.5 g / 4-dimethylaminopyridine, triethylamine / CH₂Cl₂ / 24 h / Ambient temperature

2: 1.) NaOH, Br₂; 2.) Na₂S₂O₅ / 1.) water, dioxane, 1 h, 0 deg C; 2.) water

With dmap; sodium metabisulfite; sodium hydroxide; bromine; triethylamine; In dichloromethane;
DOI:10.1002/hlca.19820650323

Reference yield:

: 83021-07-2
(S,E)-4-[4-(tert-butyldimethylsilyloxy)-2,6,6-trimethylcyclohex-1-en-1-yl]but-3-en-2-one

: 83021-08-3
(-)-3-<(R)-4-t-Butyldimethylsilyloxy-2,6,6-trimethyl-1-cyclohexen-1-yl>propensaeure

Guidance literature:: With sodium metabisulfite; sodium hydroxide; bromine; Yield given. Multistep reaction; 1.) water, dioxane, 1 h, 0 deg C; 2.) water;
DOI:10.1002/hlca.19820650323