C₄₂H₂₇Cl

Base Information

• Chemical Name: C₄₂H₂₇Cl
• CAS No.: 1439303-40-8
• Molecular Formula: C₄₂H₂₇Cl
• Molecular Weight: 567.129
• Mol file: 1439303-40-8.mol

Synonyms:C₄₂H₂₇Cl

Chemical Property of C₄₂H₂₇Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of C₄₂H₂₇Cl

There total 5 articles about C₄₂H₂₇Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

C26H16Cl2 (1401415-66-4) + 4,4,5,5-tetramethyl-2-(2-phenyl-naphthalen-1-yl)-[1,3,2]dioxaborolane (612086-25-6) → C42H27Cl (1439303-40-8)

Guidance literature:

With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In toluene; at 100 ℃; for 3h; Inert atmosphere;

Reference yield:

bromobenzene (108-86-1,52753-63-6) → C42H27Cl (1439303-40-8)

Guidance literature:

Multi-step reaction with 3 steps

1.1: magnesium / diethyl ether / 1 h / Inert atmosphere

1.2: Pd(dppf) / 8 h / 50 °C / Inert atmosphere

2.1: triethylamine; [1,1'-bis(diphenylphosphino)ferrocene]nickel(II) chloride / toluene / 5 h / 95 °C / Inert atmosphere

3.1: potassium phosphate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; bis(dibenzylideneacetone)-palladium⁽⁰⁾ / toluene / 3 h / 100 °C / Inert atmosphere

With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; [1,1'-bis(diphenylphosphino)ferrocene]nickel(II) chloride; magnesium; triethylamine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In diethyl ether; toluene;

Reference yield:

1-bromo-2-phenylnaphthalene (22082-93-5) → C42H27Cl (1439303-40-8)

Guidance literature:

Multi-step reaction with 2 steps

1: triethylamine; [1,1'-bis(diphenylphosphino)ferrocene]nickel(II) chloride / toluene / 5 h / 95 °C / Inert atmosphere

2: potassium phosphate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; bis(dibenzylideneacetone)-palladium⁽⁰⁾ / toluene / 3 h / 100 °C / Inert atmosphere

With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; [1,1'-bis(diphenylphosphino)ferrocene]nickel(II) chloride; triethylamine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In toluene;

upstream raw materials:

C₂₆H₁₆Cl₂

4,4,5,5-tetramethyl-2-(2-phenyl-naphthalen-1-yl)-[1,3,2]dioxaborolane

2,3-dichloro-anthraquinone

C₂₆H₁₈Cl₂O₂

Downstream raw materials:

C₄₂H₂₆