1-(3,3-dimethylcycloprop-1-en-1-yl)-2-[(3-nitrophenyl)methoxy]ethan-1-ol

Base Information

Chemical Name:1-(3,3-dimethylcycloprop-1-en-1-yl)-2-[(3-nitrophenyl)methoxy]ethan-1-ol
CAS No.:1434277-34-5
Molecular Formula:C₁₄H₁₇NO₄
Molecular Weight:263.293
Hs Code.:

Synonyms:1-(3,3-dimethylcycloprop-1-en-1-yl)-2-[(3-nitrophenyl)methoxy]ethan-1-ol

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Chemical Property of 1-(3,3-dimethylcycloprop-1-en-1-yl)-2-[(3-nitrophenyl)methoxy]ethan-1-ol

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Technology Process of 1-(3,3-dimethylcycloprop-1-en-1-yl)-2-[(3-nitrophenyl)methoxy]ethan-1-ol

There total 3 articles about 1-(3,3-dimethylcycloprop-1-en-1-yl)-2-[(3-nitrophenyl)methoxy]ethan-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 842136-40-7
C₉H₉NO₄

: 23534-97-6
1,1,3‐tribromo‐2,2‐dimethylcyclopropane

: 1434277-34-5
1-(3,3-dimethylcycloprop-1-en-1-yl)-2-[(3-nitrophenyl)methoxy]ethan-1-ol

Guidance literature:: 1,1,3‐tribromo‐2,2‐dimethylcyclopropane; With n-butyllithium; In diethyl ether; hexane; at -78 - -10 ℃; for 1h;

C₉H₉NO₄; In diethyl ether; hexane; at -50 - -10 ℃; for 0.333333h;
DOI:10.1002/anie.201205913

Reference yield:

: 117401-73-7
1-allyloxymethyl-3-nitrobenzene

: 1434277-34-5
1-(3,3-dimethylcycloprop-1-en-1-yl)-2-[(3-nitrophenyl)methoxy]ethan-1-ol

Guidance literature:: Multi-step reaction with 3 steps

1.1: 4-methylmorpholine N-oxide; osmium(VIII) oxide / acetone; water; tert-butyl alcohol / 18 h / 20 °C

2.1: sodium periodate / acetone; water / 3 h / 20 °C

3.1: n-butyllithium / hexane; diethyl ether / 1 h / -78 - -10 °C

3.2: 0.33 h / -50 - -10 °C

With sodium periodate; osmium(VIII) oxide; n-butyllithium; 4-methylmorpholine N-oxide; In diethyl ether; hexane; water; acetone; tert-butyl alcohol;
DOI:10.1002/anie.201205913

Reference yield:

: 3-((3-nitrobenzyl)oxy)propane-1,2-diol

: 1434277-34-5
1-(3,3-dimethylcycloprop-1-en-1-yl)-2-[(3-nitrophenyl)methoxy]ethan-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium periodate / acetone; water / 3 h / 20 °C

2.1: n-butyllithium / hexane; diethyl ether / 1 h / -78 - -10 °C

2.2: 0.33 h / -50 - -10 °C

With sodium periodate; n-butyllithium; In diethyl ether; hexane; water; acetone;
DOI:10.1002/anie.201205913