benzyl 4-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2-O-(2,3,4-tri-O-benzyl-α-L-rhamnopyranosyl)-β-L-arabinopyranoside

Base Information

Chemical Name:benzyl 4-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2-O-(2,3,4-tri-O-benzyl-α-L-rhamnopyranosyl)-β-L-arabinopyranoside
CAS No.:86049-15-2
Molecular Formula:C₆₀H₆₈O₁₈
Molecular Weight:1077.19
Hs Code.:

Synonyms:benzyl 4-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2-O-(2,3,4-tri-O-benzyl-α-L-rhamnopyranosyl)-β-L-arabinopyranoside

Suppliers and Price of benzyl 4-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2-O-(2,3,4-tri-O-benzyl-α-L-rhamnopyranosyl)-β-L-arabinopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of benzyl 4-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2-O-(2,3,4-tri-O-benzyl-α-L-rhamnopyranosyl)-β-L-arabinopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of benzyl 4-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2-O-(2,3,4-tri-O-benzyl-α-L-rhamnopyranosyl)-β-L-arabinopyranoside

There total 8 articles about benzyl 4-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2-O-(2,3,4-tri-O-benzyl-α-L-rhamnopyranosyl)-β-L-arabinopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.9%

: 86049-12-9
benzyl 4-O-benzyl-2-O-(2,3,4-tri-O-benzyl-α-L-rhamnopyranosyl)-β-L-arabinopyranoside

: 572-09-8
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

: 86049-15-2
benzyl 4-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2-O-(2,3,4-tri-O-benzyl-α-L-rhamnopyranosyl)-β-L-arabinopyranoside

Guidance literature:: With mercury(II) cyanide; In nitromethane; benzene; at 60 ℃; for 30h;
DOI:10.1016/0040-4020(82)85034-5

Reference yield:

: 39524-38-4
2,3,4-tri-O-acetyl-6-deoxy-beta-L-mannopyranosyl bromide

: 86049-15-2
benzyl 4-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2-O-(2,3,4-tri-O-benzyl-α-L-rhamnopyranosyl)-β-L-arabinopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 46.5 percent / Hg(CN)2 / benzene; nitromethane / 1 h / 45 °C

2: 1) 1N NaOMe; 2) KOH / 1) MeOH, room temp., 16 h; 2) 100 deg C, 4 h

3: 97.5 percent / LiAlH₄, AlCl₃ / CH₂Cl₂; diethyl ether / 0.25 h / Heating

4: 73.9 percent / Hg(CN)2 / benzene; nitromethane / 30 h / 60 °C

With potassium hydroxide; lithium aluminium tetrahydride; aluminium trichloride; sodium methylate; mercury(II) cyanide; In diethyl ether; nitromethane; dichloromethane; benzene;
DOI:10.1016/0040-4020(82)85034-5

Reference yield:

: 79936-12-2
benzyl endo-3,4-O-benzylidene-β-L-arabinopyranoside

: 86049-15-2
benzyl 4-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2-O-(2,3,4-tri-O-benzyl-α-L-rhamnopyranosyl)-β-L-arabinopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 46.5 percent / Hg(CN)2 / benzene; nitromethane / 1 h / 45 °C

2: 1) 1N NaOMe; 2) KOH / 1) MeOH, room temp., 16 h; 2) 100 deg C, 4 h

3: 97.5 percent / LiAlH₄, AlCl₃ / CH₂Cl₂; diethyl ether / 0.25 h / Heating

4: 73.9 percent / Hg(CN)2 / benzene; nitromethane / 30 h / 60 °C

With potassium hydroxide; lithium aluminium tetrahydride; aluminium trichloride; sodium methylate; mercury(II) cyanide; In diethyl ether; nitromethane; dichloromethane; benzene;
DOI:10.1016/0040-4020(82)85034-5