Chlordane

Base Information

• Chemical Name: Chlordane
• CAS No.: 57-74-9
• Deprecated CAS: 39400-80-1
• Molecular Formula: C10H6 Cl8
• Molecular Weight: 409.782
• Hs Code.: 29038200
• European Community (EC) Number: 200-349-0,225-826-0,225-825-5,687-155-3
• ICSC Number: 0740
• NSC Number: 8931
• UN Number: 2995,2996,2902,2762
• DSSTox Substance ID: DTXSID7020267
• Nikkaji Number: J4.407E
• Wikipedia: Chlordane
• Wikidata: Q417134
• NCI Thesaurus Code: C29814
• ChEMBL ID: CHEMBL196537
• Mol file: 57-74-9.mol

Synonyms:Chlordan;Chlordane;gamma Chlordane;gamma-Chlordane

Chemical Property of Chlordane

Chemical Property:

• Appearance/Colour: off-white powder
• Vapor Pressure: 7.72E-08mmHg at 25°C
• Melting Point: 106 - 107 C
• Refractive Index: 1.604
• Boiling Point: 449.2°Cat760mmHg
• Flash Point: 229.6°C
• PSA: 0.00000
• Density: 1.75g/cm³
• LogP: 5.68280
• Storage Temp.: 0-6°C
• Solubility.: Miscible with acetone, cyclohexanone, deodorized kerosene, ethanol, 2-propanol, trichloroethylene (Worthing and Hance, 1991)
• Water Solubility.: 0.1 mg l-1(25 °C)
• XLogP3: 4.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 409.791872
• Heavy Atom Count: 18
• Complexity: 459
• Transport DOT Label: Poison Flammable Liquid

Purity/Quality:

98%min ^*data from raw suppliers

CD68 ^*data from reagent suppliers

Safty Information:

• Pictogram(s): An animal carcinogen. Toxic by ingestion, inhalation, and skin absorption. TLV: 0.5 mg/m³.
• Hazard Codes: Xn,N,Xi,F,T
• Statements: 21/22-40-50/53-36/37/38-11-39/23/24/25-23/24/25-67-65-38
• Safety Statements: 36/37-60-61-36-33-26-16-45-7-62-29-9

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Pesticides -> Organochlorine Pesticides
• Canonical SMILES: C1C2C(C(C1Cl)Cl)C3(C(=C(C2(C3(Cl)Cl)Cl)Cl)Cl)Cl
• Inhalation Risk: Evaporation at 20 °C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying.
• Effects of Short Term Exposure: Exposure at high levels could cause disorientation, tremors, convulsions, respiratory failure and death. Medical observation is indicated.
• Effects of Long Term Exposure: The substance may have effects on the liver and immune system. This may result in tissue lesions and liver impairment. This substance is possibly carcinogenic to humans.
• Description: Chlordane is a viscous, amber-coloured liquid. Technical-grade chlordane is a mixture of many structurally related compounds including trans-chlordane, cis-chlordane, chlordene, heptachlor, and trans-nonachlor. Chlordane was used as a broad-spectrum pesticide in the United States from 1948 to 1988. The uses included termite control in homes and pest control on agricultural crops such as maize and citrus, on home lawns, gardens, turf, and ornamental plants. Chlordane is a persistent organochlorine insecticide. It kills insects when ingested and on contact. Formulations include dusts, emulsifiable concentrates, granules, oil solutions, and wettable powder.
• Physical properties: Colorless to amber to yellowish-brown, viscous liquid. Technical formulations impart an aromatic, slight pungent odor similar to chlorine
• Uses: Chlordane is a persistent non-systemic contact and ingested insecticide with some fumigant action. It is used as a wood preservative, protective treatment for underground cables, and to reduce earthworm populations in lawns. It is used against Formicidae, Coleoptera, Noctuidae larva, Saltatoria, subterranean termites, and many other insect pests. It controls household insects, pests of man and domestic animals. Insecticide and fumigant. Insecticide, fumigant.

Technology Process of Chlordane

There total 3 articles about Chlordane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ chlordane (57-74-9)

Guidance literature:

Reference yield:

→ trans-chlordane (57-74-9,5103-71-9,5103-74-2,24143-43-9,66429-41-2,66514-87-2,66514-88-3,142433-24-7)

Guidance literature:

With tetrachloromethane; chlorine;

Reference yield:

chlordene (3734-48-3) → trans-chlordane (57-74-9,5103-71-9,5103-74-2,24143-43-9,66429-41-2,66514-87-2,66514-88-3,142433-24-7)

Guidance literature:

With iron(III) chloride; chlorothio-trichloro-methane; at 150 ℃;

upstream raw materials:

chlordene

Refernces