bis(1-ethylpropyl) hexanedioate

Base Information

• Chemical Name: bis(1-ethylpropyl) hexanedioate
• CAS No.: 101434-25-7
• Molecular Formula: C₁₆H₃₀O₄
• Molecular Weight: 286.412
• Mol file: 101434-25-7.mol

Synonyms:adipic acid di(3-pentyl) ester

Chemical Property of bis(1-ethylpropyl) hexanedioate

Chemical Property:

• Vapor Pressure: 0.00069mmHg at 25°C

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(1-ethylpropyl) hexanedioate

There total 3 articles about bis(1-ethylpropyl) hexanedioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

2-pentanol (584-02-1) + carbon monoxide (201230-82-2) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) → adipic acid di(3-pentyl) ester (101434-25-7)

Guidance literature:

With palladium(II) trifluoroacetate; toluene-4-sulfonic acid; 1,2-bis[di(t-butyl)phosphinomethyl]benzene; In toluene; at 120 ℃; for 24h; under 30003 Torr; regioselective reaction; Autoclave; Green chemistry;

DOI:10.1002/anie.202015329

Reference yield:

meso-galactaric acid (526-99-8,1213827-87-2,7231-46-1) + 2-pentanol (584-02-1) → adipic acid di(3-pentyl) ester (101434-25-7) + C11H20O4 (855605-57-1)

Guidance literature:

meso-galactaric acid; 2-pentanol; With methyltrioxorhenium(VII); toluene-4-sulfonic acid; at 120 ℃; for 12h;

With platinum on carbon; hydrogen; at 160 ℃; for 12h; Reagent/catalyst; Temperature; Time;

DOI:10.1002/anie.201310991

Reference yield:

Adipic acid (124-04-9) + 2-pentanol (584-02-1) → adipic acid di(3-pentyl) ester (101434-25-7)

Guidance literature:

With toluene-4-sulfonic acid;

DOI:10.1021/ja01102a043

upstream raw materials:

Adipic acid

2-pentanol

meso-galactaric acid

carbon monoxide

Downstream raw materials:

Adipic acid