phenyl 2-azido-2-deoxy-4,6-O-(1-naphthylmethylidene)-1-thio-β-D-glucopyranoside

Base Information

• Chemical Name: phenyl 2-azido-2-deoxy-4,6-O-(1-naphthylmethylidene)-1-thio-β-D-glucopyranoside
• CAS No.: 1075217-38-7
• Molecular Formula: C₂₃H₂₁N₃O₄S
• Molecular Weight: 435.503
• Mol file: 1075217-38-7.mol

Synonyms:phenyl 2-azido-2-deoxy-4,6-O-(1-naphthylmethylidene)-1-thio-β-D-glucopyranoside

Chemical Property of phenyl 2-azido-2-deoxy-4,6-O-(1-naphthylmethylidene)-1-thio-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of phenyl 2-azido-2-deoxy-4,6-O-(1-naphthylmethylidene)-1-thio-β-D-glucopyranoside

There total 1 articles about phenyl 2-azido-2-deoxy-4,6-O-(1-naphthylmethylidene)-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

1-(dimethoxymethyl)naphthalene (33250-32-7) + phenyl 2-azido-2-deoxy-1-thio-β-D-glucopyranoside (166516-67-2) → phenyl 2-azido-2-deoxy-4,6-O-(1-naphthylmethylidene)-1-thio-β-D-glucopyranoside (1075217-38-7)

Guidance literature:

With 10-camphorsufonic acid; In N,N-dimethyl-formamide; at 50 ℃; for 5h; under 300.03 Torr;

DOI:10.1016/j.tet.2008.08.021

Reference yield: 86.0%

phenyl 2-azido-2-deoxy-4,6-O-(1-naphthylmethylidene)-1-thio-β-D-glucopyranoside (1075217-38-7) + benzyl bromide (100-39-0) → phenyl 2-azido-3-O-benzyl-2-deoxy-4,6-O-(1-naphthylmethylidene)-1-thio-β-D-glucopyranoside (1075217-39-8)

Guidance literature:

phenyl 2-azido-2-deoxy-4,6-O-(1-naphthylmethylidene)-1-thio-β-D-glucopyranoside; With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 0 ℃; for 0.5h;

benzyl bromide; In N,N-dimethyl-formamide; mineral oil; for 2h;

DOI:10.1016/j.tet.2008.08.021

upstream raw materials:

1-(dimethoxymethyl)naphthalene

phenyl 2-azido-2-deoxy-1-thio-β-D-glucopyranoside

Downstream raw materials:

phenyl 2-azido-3-O-benzyl-2-deoxy-4,6-O-(1-naphthylmethylidene)-1-thio-β-D-glucopyranoside