(2R,3R,4R,6R)-6-((S)-4-((tert-butyldiphenylsilyl)oxy)-2-methyl-3-((triethylsilyl)oxy)butan-2-yl)-2-methoxy-2-(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)-oxy)tetrahydro-2H-pyran-2-yl)methyl)-4-methyltetrahydro-2H-pyran-3-ol

Base Information

Chemical Name:(2R,3R,4R,6R)-6-((S)-4-((tert-butyldiphenylsilyl)oxy)-2-methyl-3-((triethylsilyl)oxy)butan-2-yl)-2-methoxy-2-(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)-oxy)tetrahydro-2H-pyran-2-yl)methyl)-4-methyltetrahydro-2H-pyran-3-ol
CAS No.:1381848-80-1
Molecular Formula:C₆₀H₁₀₀O₉Si₃
Molecular Weight:1049.71
Hs Code.:

(2R,3R,4R,6R)-6-((S)-4-((tert-butyldiphenylsilyl)oxy)-2-methyl-3-((triethylsilyl)oxy)butan-2-yl)-2-methoxy-2-(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)-oxy)tetrahydro-2H-pyran-2-yl)methyl)-4-methyltetrahydro-2H-pyran-3-ol

Synonyms:(2R,3R,4R,6R)-6-((S)-4-((tert-butyldiphenylsilyl)oxy)-2-methyl-3-((triethylsilyl)oxy)butan-2-yl)-2-methoxy-2-(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)-oxy)tetrahydro-2H-pyran-2-yl)methyl)-4-methyltetrahydro-2H-pyran-3-ol

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Chemical Property of (2R,3R,4R,6R)-6-((S)-4-((tert-butyldiphenylsilyl)oxy)-2-methyl-3-((triethylsilyl)oxy)butan-2-yl)-2-methoxy-2-(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)-oxy)tetrahydro-2H-pyran-2-yl)methyl)-4-methyltetrahydro-2H-pyran-3-ol

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Technology Process of (2R,3R,4R,6R)-6-((S)-4-((tert-butyldiphenylsilyl)oxy)-2-methyl-3-((triethylsilyl)oxy)butan-2-yl)-2-methoxy-2-(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)-oxy)tetrahydro-2H-pyran-2-yl)methyl)-4-methyltetrahydro-2H-pyran-3-ol

There total 28 articles about (2R,3R,4R,6R)-6-((S)-4-((tert-butyldiphenylsilyl)oxy)-2-methyl-3-((triethylsilyl)oxy)butan-2-yl)-2-methoxy-2-(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)-oxy)tetrahydro-2H-pyran-2-yl)methyl)-4-methyltetrahydro-2H-pyran-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 1381848-75-4
C₅₉H₉₆O₇Si₃

: 1381848-80-1
(2R,3R,4R,6R)-6-((S)-4-((tert-butyldiphenylsilyl)oxy)-2-methyl-3-((triethylsilyl)oxy)butan-2-yl)-2-methoxy-2-(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)-oxy)tetrahydro-2H-pyran-2-yl)methyl)-4-methyltetrahydro-2H-pyran-3-ol

: 1381848-79-8
(2R,3S,4R,6R)-6-((S)-4-((tert-butyldiphenylsilyl)oxy)-2-methyl-3-((triethylsilyl)oxy)butan-2-yl)-2-methoxy-2-(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)oxy)-tetrahydro-2H-pyran-2-yl)methyl)-4-methyltetrahydro-2H-pyran-3-ol

Guidance literature:: With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In methanol; dichloromethane; at 0 ℃; for 1.5h;
DOI:10.1021/ol301278e

Reference yield:

: 1381848-54-9
C₂₆H₄₆O₅Si₂

: 1381848-80-1
(2R,3R,4R,6R)-6-((S)-4-((tert-butyldiphenylsilyl)oxy)-2-methyl-3-((triethylsilyl)oxy)butan-2-yl)-2-methoxy-2-(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)-oxy)tetrahydro-2H-pyran-2-yl)methyl)-4-methyltetrahydro-2H-pyran-3-ol

Guidance literature:: Multi-step reaction with 8 steps

1.1: potassium carbonate / methanol / 0.5 h / 20 °C

1.2: 20 °C

2.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0.67 h / -20 °C

3.1: 2,6-dimethylpyridine / dichloromethane / 1 h / 0 °C

4.1: camphor-10-sulfonic acid / methanol; dichloromethane / 1 h / 0 °C

5.1: 1H-imidazole; iodine; triphenylphosphine / tetrahydrofuran / 2 h / 20 °C

6.1: potassium tert-butylate / tetrahydrofuran / 0.67 h / 0 °C

7.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 2 h / 0 - 20 °C

7.2: 0.67 h

7.3: 14 h / 20 °C

8.1: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / methanol; dichloromethane / 1.5 h / 0 °C

With 1H-imidazole; 2,6-dimethylpyridine; sodium tetrahydroborate; cerium(III) chloride heptahydrate; camphor-10-sulfonic acid; potassium tert-butylate; iodine; sodium hydrogencarbonate; potassium carbonate; 9-bora-bicyclo[3.3.1]nonane; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/ol301278e

Reference yield:

: 1381848-61-8
triisopropyl(((2S,3S,4S)-2-(2-((4-methoxybenzyl)oxy)ethyl)-3-methyl-6-methylenetetrahydro-2H-pyran-4-yl)oxy)silane

: 1381848-80-1
(2R,3R,4R,6R)-6-((S)-4-((tert-butyldiphenylsilyl)oxy)-2-methyl-3-((triethylsilyl)oxy)butan-2-yl)-2-methoxy-2-(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)-oxy)tetrahydro-2H-pyran-2-yl)methyl)-4-methyltetrahydro-2H-pyran-3-ol

Guidance literature:: Multi-step reaction with 2 steps

1.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 2 h / 0 - 20 °C

1.2: 0.67 h

1.3: 14 h / 20 °C

2.1: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / methanol; dichloromethane / 1.5 h / 0 °C

With sodium hydrogencarbonate; 9-bora-bicyclo[3.3.1]nonane; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/ol301278e