13-tert-butyl-13-cis-retinal

Base Information

Chemical Name:13-tert-butyl-13-cis-retinal
CAS No.:106190-63-0
Molecular Formula:C₂₃H₃₄O
Molecular Weight:326.522
Hs Code.:

Synonyms:13-tert-butyl-13-cis-retinal

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Chemical Property of 13-tert-butyl-13-cis-retinal

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Technology Process of 13-tert-butyl-13-cis-retinal

There total 12 articles about 13-tert-butyl-13-cis-retinal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

: 120591-35-7
13-tert-butyl-11,12-allenic retinal

: 113775-89-6
(2E,4Z,6E,8E)-3-tert-Butyl-7-methyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraenal

: 106190-63-0
13-tert-butyl-13-cis-retinal

Guidance literature:: With sodium ethanolate; In ethanol; at 0 ℃; for 2h; Product distribution; variation of reagents, solvent, reaction temperature and time;
DOI:10.1016/S0040-4039(00)80268-3

Reference yield:

: 106140-74-3,111917-89-6,111917-92-1
3-methyl-1-(2,6,6-trimethylcyclohexen-1-yl)-1,3,5-octatrien-7-yne

: 106140-78-7,106190-63-0,113775-89-6,115113-82-1,115113-83-2
13-cis-20-nor-13-tert-butylretinal

Guidance literature:: Multi-step reaction with 7 steps

1: 1.) n-butyllithium / 1.) Et₂O, hexane, from -78 deg C to -50 deg C, 2.) Et₂O, hexane, a) -30 deg C, 2 h, b) from -30 deg C to RT, 4 h

2: 1.) copper(I) iodide / 1.) THF, Et₂O, 0 deg C, 2.) THF, Et₂O, -78 deg C, 2 h

3: LiAlH₄ / diethyl ether / 2 h / -30 °C

4: MnO₂ / diethyl ether / 15 h

5: 1.) copper(I) iodide / 1.) THF, pentane, -30 deg C, 2.) THF, pentane, -78 deg C, 2 h

6: LiAlH₄ / diethyl ether / 2 h / -30 °C

7: MnO₂ / diethyl ether / 15 h

With manganese(IV) oxide; copper(l) iodide; lithium aluminium tetrahydride; n-butyllithium; In diethyl ether;
DOI:10.1021/jo00379a016

Reference yield:

: (2Z,4E,6E,8E)-3-Ethyl-7-methyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraen-1-ol

: 106140-78-7,106190-63-0,113775-89-6,115113-82-1,115113-83-2
13-cis-20-nor-13-tert-butylretinal

Guidance literature:: Multi-step reaction with 4 steps

1: MnO₂ / diethyl ether / 15 h

2: 1.) copper(I) iodide / 1.) THF, pentane, -30 deg C, 2.) THF, pentane, -78 deg C, 2 h

3: LiAlH₄ / diethyl ether / 2 h / -30 °C

4: MnO₂ / diethyl ether / 15 h

With manganese(IV) oxide; copper(l) iodide; lithium aluminium tetrahydride; In diethyl ether;
DOI:10.1021/jo00379a016