2,2',2''-trisphenylamidotriphenylamine

Base Information

• Chemical Name: 2,2',2''-trisphenylamidotriphenylamine
• CAS No.: 1202463-89-5
• Molecular Formula: C₃₉H₃₀N₄O₃
• Molecular Weight: 602.692
• Mol file: 1202463-89-5.mol

Synonyms:2,2',2''-trisphenylamidotriphenylamine

Chemical Property of 2,2',2''-trisphenylamidotriphenylamine

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,2',2''-trisphenylamidotriphenylamine

There total 1 articles about 2,2',2''-trisphenylamidotriphenylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

N1,N1-bis(2-aminophenyl)benzene-1,2-diamine (953389-63-4) + benzoyl chloride (98-88-4) → 2,2',2''-trisphenylamidotriphenylamine (1202463-89-5)

Guidance literature:

With triethylamine; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1021/ic9015838

Reference yield: 66.0%

2,2',2''-trisphenylamidotriphenylamine (1202463-89-5) + tetraphenylphosphonium bromide (2751-90-8) + potassium hydride + acetonitrile (75-05-8,26809-02-9) + nickel dibromide (13462-88-9) → [Ph4P][Ni(2,2',2''-trisphenylamidotriphenylamine(-3H))(acetonitrile)] (1207997-84-9)

Guidance literature:

In N,N-dimethyl-formamide; byproducts: H2, KBr; (N2); KH added to a soln. of ligand, reacted for ca 30 min, NiBr2 added,dissolved for 4 h, P(C6H5)4Br added, stirred for 30 min; evapd. (vac.), dissolved in MeCN, filtered, concd. (vac.), recrystd. (MeCN); elem. anal.;

DOI:10.1039/b914301g

Reference yield: 65.0%

2,2',2''-trisphenylamidotriphenylamine (1202463-89-5) + potassium hydride + acetonitrile (75-05-8,26809-02-9) + iron(II) chloride → [K(acetonitrile)][(((phenyl-CO)-N-(2-C6H4))3N)Fe(II)(acetonitrile)]*2(acetonitrile)

Guidance literature:

In tetrahydrofuran; byproducts: KCl; under N2 or Ar; ligand dissolved in degassed THF; KH added; stirred overnight; anhyd. FeCl2 added; stirred for 12 h; solvent reduced under vac.;refrigerated (-30°C) overnight; filtered; filtrate evapd. to dry ness under vac.; dissolved in MeCN; filtered; filtrate reduced; crystd. overnight; elem. anal.;

DOI:10.1021/ic9015838

upstream raw materials:

N¹,N¹-bis(2-aminophenyl)benzene-1,2-diamine

benzoyl chloride

Downstream raw materials:

[Ph₄P][Ni(2,2',2''-trisphenylamidotriphenylamine(-3H))(acetonitrile)]