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N-[1-[(6-chloro-3-pyridinyl)methyl]-4,5-dihydroimidazol-2-yl]nitramide

Base Information Edit
  • Chemical Name:N-[1-[(6-chloro-3-pyridinyl)methyl]-4,5-dihydroimidazol-2-yl]nitramide
  • CAS No.:138261-41-3
  • Molecular Formula:C9H10ClN5O2
  • Molecular Weight:255.664
  • Hs Code.:29333990
  • UNII:3BN7M937V8
  • Mol file:138261-41-3.mol
N-[1-[(6-chloro-3-pyridinyl)methyl]-4,5-dihydroimidazol-2-yl]nitramide

Synonyms:105827-78-9;N-[1-[(6-chloro-3-pyridinyl)methyl]-4,5-dihydroimidazol-2-yl]nitramide;N-[1-[(6-chloropyridin-3-yl)methyl]-4,5-dihydroimidazol-2-yl]nitramide;1-((6-Chloro-3-pyridinyl)methyl)-4,5-dihydro-N-nitro-imidazol-2-amine;1-((6-chloro-3-pyridinyl)methyl)-n-nitro-4,5-dihydro-1h-imidazol-2-amine;1-((6-Chloro-3-pyridinyl)methyl)-4,5-dihydro-N-nitro-1H-imidazol-2-amine;1-[(6-chloro-3-pyridinyl)methyl]-4,5-dihydro-N-nitro-1H-imidazol-2-amine;IMIDACLOPRID [MI];IMIDACLOPRID [HSDB];C9H10ClN5O2;MLS001304087;IMIDACLOPRID [GREEN BOOK];HMS2231F05;HMS3373H06;BDBM50212288;MFCD00468059;AKOS015895351;CS-T-29156;SMR000718777;FT-0631157;FT-0656073;E79264;AB00876233-04;A801327;J-007111;1-(6-chloro-3-pyridylmethyl)-N-nitromidazolidin-2-ylideneamine;1-[(6-Chloropyridin-3-yl)methyl]-N-nitro-4,5-dihydro-1H-imidazol-2-amine;2-chloro-5-{[2-(nitroamino)-4,5-dihydro-1H-imidazol-1-yl]methyl}pyridine;2-Imidazolidinimina, 1-[(6-cloro-3-piridil) metil]-N-nitro-, (2E)-;N-[1-[(6-chloranylpyridin-3-yl)methyl]-4,5-dihydroimidazol-2-yl]nitramide;N-{1-[(6-Chloro-3-pyridyl)methyl]-4,5-dihydroimidazol-2-yl}nitramide;imidacloprid (ISO);1-(6-chloropyridin-3-ylmethyl)-N-nitroimidazolidin-2-ylidenamine;N-(1-((6-chloropyridin-3-yl)methyl)-4,5-dihydro-1H-imidazol-2-yl)nitramide

Suppliers and Price of N-[1-[(6-chloro-3-pyridinyl)methyl]-4,5-dihydroimidazol-2-yl]nitramide
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • TRC
  • Imidacloprid
  • 5g
  • $ 460.00
  • TRC
  • Imidacloprid
  • 250mg
  • $ 135.00
  • Sigma-Aldrich
  • Imidacloprid PESTANAL
  • 100mg
  • $ 72.40
  • Sigma-Aldrich
  • Imidacloprid solution 100μg/mL in acetonitrile, PESTANAL
  • 2ml
  • $ 61.10
  • Medical Isotopes, Inc.
  • Imidacloprid-d4(imidazolidine-4,4,5,5-d4)
  • 5 mg
  • $ 290.00
  • Matrix Scientific
  • (2E)-1-[(6-Chloropyridin-3-yl)methyl]-N-nitroimidazolidin-2-imine
  • 1g
  • $ 168.00
  • Matrix Scientific
  • (2E)-1-[(6-Chloropyridin-3-yl)methyl]-N-nitroimidazolidin-2-imine
  • 500mg
  • $ 142.00
  • Matrix Scientific
  • (2E)-1-[(6-Chloropyridin-3-yl)methyl]-N-nitroimidazolidin-2-imine
  • 5g
  • $ 557.00
  • Cayman Chemical
  • Imidacloprid ≥98%
  • 50mg
  • $ 42.00
  • Cayman Chemical
  • Imidacloprid ≥98%
  • 100mg
  • $ 62.00
Total 238 raw suppliers
Chemical Property of N-[1-[(6-chloro-3-pyridinyl)methyl]-4,5-dihydroimidazol-2-yl]nitramide Edit
Chemical Property:
  • Appearance/Colour:COA 
  • Vapor Pressure:5.47E-07mmHg at 25°C 
  • Melting Point:144 ºC 
  • Refractive Index:1.713 
  • Boiling Point:442.3 ºC at 760 mmHg 
  • PKA:7.16±0.20(Predicted) 
  • Flash Point:221.3 ºC 
  • PSA:89.04000 
  • Density:1.59 g/cm3 
  • LogP:1.47780 
  • Storage Temp.:0-6°C 
  • Water Solubility.:0.061 g/100mL at 20 ºC 
  • XLogP3:0.8
  • Hydrogen Bond Donor Count:1
  • Hydrogen Bond Acceptor Count:4
  • Rotatable Bond Count:3
  • Exact Mass:255.0523023
  • Heavy Atom Count:17
  • Complexity:319
Purity/Quality:

99% *data from raw suppliers

Imidacloprid *data from reagent suppliers

Safty Information:
  • Pictogram(s): DangerousN,HarmfulXn,Flammable
  • Hazard Codes:N,Xn,F 
  • Statements: 11-20/21/22-36-22-20/22 
  • Safety Statements: 26-36-22-36/37-16-46-44 
MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:
  • Canonical SMILES:C1CN(C(=N1)N[N+](=O)[O-])CC2=CN=C(C=C2)Cl
  • Uses Imidacloprid is the active ingredient in AdvantageTM used to control fleas in dogs and cats (HSDB, 2006). Clothianidin is the major metabolite of thiamethoxam and both compounds are registered for use as insecticides. Widespread use increased greatly in the 1990s as alternatives to organophosphosphorus and carbamate insecticides because of their much lower mammalian toxicity and resistance developed to other pesticides. Imidacloprid has become the most widespread insecticide used in the world. A neonicotinoid; the active ingredient in certain neuro-active insecticides. Reports show that when exposed to neonicotinid pesticides honeybees have probelms returnign home after foraging and bumble bee colonies grow poorly and produce fewer queens. The four neonicotinoids are acetamiprid (l),imidacloprid (2), nitenpyram (3) and thiamethoxam (4) (IS0 draft proposal name). They are potent broad spectrum insecticides possessing contact, stomach and systemic activity. The structures are given below and consist of substituted aromatic heterocyclic rings: 6-chloropyridinyl for acetamiprid, imidacloprid and nitenpyram and 3-chlorothiazole for thiamethoxam. Each compound has a methylene bridge, to a cyclic nitroguanidine moiety in imidacloprid and thiamethoxam, to a cyanoamidine in acetamiprid or to a diaminonitroethylene group in nitenpyram. The terminal group for all compounds is a strong electron-withdrawing substituent on an ethene or imino group. These insecticides are used for foliar and soil application but imidacloprid also has a very high usage as a seed treatment. They have low rates of application: for example thiamethoxam is typically applied to foliage at rates of only 2.5-50 g ha-1. The neonicotinoids are polar, nonvolatile solids with high water solubilities and they are non-ionised at pH values typically found in the environment. The insecticides are not readily hydrolysed. Their polar nature makes them potentially mobile in soil but this is mitigated by their low rates of application and, for acetamiprid and nitenpyram, short persistence. hnidacloprid and thiamethoxam are sufficiently persistent to be used as soil treaments. All the insecticides are efficiently translocated in plants and are effective systemic agents against sucking pests.
Technology Process of N-[1-[(6-chloro-3-pyridinyl)methyl]-4,5-dihydroimidazol-2-yl]nitramide

There total 7 articles about N-[1-[(6-chloro-3-pyridinyl)methyl]-4,5-dihydroimidazol-2-yl]nitramide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With dmap; In 5,5-dimethyl-1,3-cyclohexadiene; at 106 - 110 ℃; for 5h; Reagent/catalyst; Temperature;
Guidance literature:
In dichloromethane;
Refernces Edit
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