Piperidine pentamethylenedithiocarbamate

Base Information

• Chemical Name: Piperidine pentamethylenedithiocarbamate
• CAS No.: 98-77-1
• Molecular Formula: C6H11NS2^.C5H11N
• Molecular Weight: 246.441
• Hs Code.: 2933399090
• Mol file: 98-77-1.mol

Synonyms:PMP (accelerator);1-Piperidinecarbodithioic acid, compd. with piperidine (1:1);1-Piperidinecarbodithioic acid, piperidine salt;Accelerator 552;1-Piperidinecarbodithioic acid, piperidine salt (6CI);1-Piperidinecarbodithioic acid,compd. with piperidine (1:1);PMP(VAN);Piperidinium piperidine-1-carbodithioate;522 Rubber accelerator;piperidine; piperidine-1-carbodithioic acid;Nocceler PPD;522;Pentamethyleneammonium pentamethylenedithiocarbamate;1-Piperidinecarbodithioic acid, compound with piperidine (1:1);

Chemical Property of Piperidine pentamethylenedithiocarbamate

Chemical Property:

• Appearance/Colour: Creamy white to light yellow Power
• Vapor Pressure: 0.106mmHg at 25°C
• Melting Point: 172-173 °C
• Boiling Point: 221.6 °C at 760 mmHg
• Flash Point: 87.8 °C
• PSA: 86.16000
• Density: g/cm³
• LogP: 2.71360
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 246.12244106
• Heavy Atom Count: 15
• Complexity: 133

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-Piperidinecarbodithioic acid piperidine salt ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1CC[NH2+]CC1.C1CCN(CC1)C(=S)[S-]

Technology Process of Piperidine pentamethylenedithiocarbamate

There total 8 articles about Piperidine pentamethylenedithiocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

piperidine (110-89-4) + carbon disulfide (75-15-0,12122-00-8) → piperidinium piperidyldithiocarbamate (98-77-1)

Guidance literature:

In diethyl ether; at 20 ℃; for 0.5h;

DOI:10.1080/17415993.2016.1166225

Reference yield: 93.0%

piperidine (110-89-4) + Thiram (137-26-8,93196-73-7) → N-(N,N-dimethylthiocarbamoyldithioyl)piperidine (66232-66-4) + piperidinium piperidyldithiocarbamate (98-77-1) + piperidinium N,N-dimethyldithiocarbamate

Guidance literature:

at 20 ℃; for 3h;

DOI:10.1007/BF02498275

Reference yield: 64.4%

piperidinium N,N-dimethyldithiocarbamate → piperidinium piperidyldithiocarbamate (98-77-1)

Guidance literature:

Further Variations:; Solvents; Temperatures; Product distribution; Heating;

DOI:10.1007/BF02494685

upstream raw materials:

piperidine

carbon disulfide

1,1-diphenylthiourea

Thiram

Downstream raw materials:

1,1'-phthaloyl-bis-piperidine

Piperidine-1-carbodithioic acid 2-[(E)-hydroxyimino]-2-phenyl-ethyl ester

Piperidine-1-carbodithioic acid 2-[(Z)-hydroxyimino]-2-phenyl-ethyl ester

Piperidine-1-carbodithioic acid 3-oxo-1-phenyl-butyl ester