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98-77-1

Basic Information
CAS No.: 98-77-1
Name: Piperidine pentamethylenedithiocarbamate
Article Data: 22
Molecular Structure:
Molecular Structure of 98-77-1 (Piperidine pentamethylenedithiocarbamate)
Formula: C6H11NS2.C5H11N
Molecular Weight: 246.441
Synonyms: PMP (accelerator);1-Piperidinecarbodithioic acid, compd. with piperidine (1:1);1-Piperidinecarbodithioic acid, piperidine salt;Accelerator 552;1-Piperidinecarbodithioic acid, piperidine salt (6CI);1-Piperidinecarbodithioic acid,compd. with piperidine (1:1);PMP(VAN);Piperidinium piperidine-1-carbodithioate;522 Rubber accelerator;piperidine; piperidine-1-carbodithioic acid;Nocceler PPD;522;Pentamethyleneammonium pentamethylenedithiocarbamate;1-Piperidinecarbodithioic acid, compound with piperidine (1:1);
EINECS: 202-698-4
Density: g/cm3
Melting Point: 172-173 °C
Boiling Point: 221.6 °C at 760 mmHg
Flash Point: 87.8 °C
Appearance: Creamy white to light yellow Power
PSA: 86.16000
LogP: 2.71360
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Chemistry

Molecular Structure of Piperidine pentamethylenedithiocarbamate (CAS NO.98-77-1):

IUPAC Name: piperidine; piperidine-1-carbodithioic acid
Molecular Formula: C11H22N2S2
Molecular Weight: 246.44
EINECS: 202-698-4
H bond acceptors: 1
H bond donors: 0
Freely Rotating Bonds: 0
Polar Surface Area: 60.63 Å2
Flash Point: 87.8 °C
Enthalpy of Vaporization: 45.81 kJ/mol
Boiling Point: 221.6 °C at 760 mmHg
Vapour Pressure: 0.106 mmHg at 25 °C
InChI: InChI=1/C6H11NS2.C5H11N/c8-6(9)7-4-2-1-3-5-7;1-2-4-6-5-3-1/h1-5H2,(H,8,9);6H,1-5H2
Smiles: C(N1CCCCC1)(=S)S.N1CCCCC1
Classification Code: Skin / Eye Irritant

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mammal (species unspecified) LD50 intraperitoneal 250mg/kg (250mg/kg) BRAIN AND COVERINGS: OTHER DEGENERATIVE CHANGES

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

CARDIAC: OTHER CHANGES
AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 5, Pg. 311, 1952.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intraperitoneal route. A human skin irritant. An allergen. When heated to decomposition it emits very toxic fumes of NOx and SOx.
RIDADR: 2811
HazardClass: 6.1(b)
PackingGroup: III

Specification

  Piperidine pentamethylenedithiocarbamate , with CAS number of 98-77-1, can be called Piperidine-1-carbodithioic acid - piperidine (1:1) ; 1-piperidinecarbodithioic acid, compd. with piperidine (1:1) ; piperidinium tetrahydropyridine-1(2H)-carbodithioate . Piperidine pentamethylenedithiocarbamate (CAS NO.98-77-1) is commonly used for NR, IR, BR, SBR, NBR, EPDM and latex, which is one of the super speed promoters. It's no pollution, no changed color. It's also applicable at the low-temperature for rubber or RTV.