methyl 2,3-anhydro-6-O-tert-butyldimethylsilyl-4-O-[(E)-2'-(phenylsulfonyl)vinyl]-α-D-allopyranoside

Base Information

Chemical Name:methyl 2,3-anhydro-6-O-tert-butyldimethylsilyl-4-O-[(E)-2'-(phenylsulfonyl)vinyl]-α-D-allopyranoside
CAS No.:1353644-96-8
Molecular Formula:C₂₁H₃₂O₇SSi
Molecular Weight:456.632
Hs Code.:

Synonyms:methyl 2,3-anhydro-6-O-tert-butyldimethylsilyl-4-O-[(E)-2'-(phenylsulfonyl)vinyl]-α-D-allopyranoside

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Chemical Property of methyl 2,3-anhydro-6-O-tert-butyldimethylsilyl-4-O-[(E)-2'-(phenylsulfonyl)vinyl]-α-D-allopyranoside

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Technology Process of methyl 2,3-anhydro-6-O-tert-butyldimethylsilyl-4-O-[(E)-2'-(phenylsulfonyl)vinyl]-α-D-allopyranoside

There total 1 articles about methyl 2,3-anhydro-6-O-tert-butyldimethylsilyl-4-O-[(E)-2'-(phenylsulfonyl)vinyl]-α-D-allopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 280557-39-3
Methyl 2,3-anhydro-4,6-O-(2-phenylsulfonyl)ethylidene-α-D-allopyranoside

: 1353644-95-7
methyl 2,3-anhydro-6-O-[(E)-2'-(phenylsulfonyl)vinyl]-α-D-allopyranoside

: 1353644-96-8
methyl 2,3-anhydro-6-O-tert-butyldimethylsilyl-4-O-[(E)-2'-(phenylsulfonyl)vinyl]-α-D-allopyranoside

Guidance literature:: Methyl 2,3-anhydro-4,6-O-(2-phenylsulfonyl)ethylidene-α-D-allopyranoside; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; Inert atmosphere;

With acetic acid; In tetrahydrofuran; hexane; at -78 - 20 ℃; Inert atmosphere;

tert-butyldimethylsilyl chloride; With dmap; triethylamine; In N,N-dimethyl-formamide; at 0 - 20 ℃; stereoselective reaction; Inert atmosphere;
DOI:10.1016/j.tet.2011.11.009