(η(5)-Cp)Fe(CO)(H)(PPh2Me)

Base Information

• Chemical Name: (η(5)-Cp)Fe(CO)(H)(PPh2Me)
• CAS No.: 168841-57-4
• Molecular Formula: C₁₉H₁₉FeOP
• Molecular Weight: 350.18
• Mol file: 168841-57-4.mol

Synonyms:(η(5)-Cp)Fe(CO)(H)(PPh2Me)

Chemical Property of (η(5)-Cp)Fe(CO)(H)(PPh2Me)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η(5)-Cp)Fe(CO)(H)(PPh2Me)

There total 2 articles about (η(5)-Cp)Fe(CO)(H)(PPh2Me) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

lithium aluminium tetrahydride (16853-85-3) + dicarbonylcyclopentadienyliodoiron(II) (12078-28-3,38979-86-1) + diphenyl(methyl)phosphine (1486-28-8) → (η(5)-Cp)Fe(CO)(H)(PPh2Me) (168841-57-4)

Guidance literature:

In diethyl ether; N2-atmosphere; addn. of Fe-complex to suspension of LiAlH4 at room temp., stirring for 15 min, addn. pf phosphine at -20°C, stirring for 20 min, warming to room temp.; addn. of H2O, drying org. layer (MgSO4), filtration, evapn. at -5°C, chromy. (TLC, SiO2, C6H6:hexane 3:1); elem. anal.;

DOI:10.1021/om00009a008

Reference yield:

sodium tetrahydroborate (16940-66-2) + (η5-C5H5)Fe(CO)(PMePh2)I → (η(5)-Cp)Fe(CO)(H)(PPh2Me) (168841-57-4)

Guidance literature:

In tetrahydrofuran; at 60 ℃;

DOI:10.1016/j.poly.2018.09.062

Reference yield: 21.0%

(η(5)-Cp)Fe(CO)(H)(PPh2Me) (168841-57-4) + C54H74Cu2N4 → C46H54CuFeN2OP

Guidance literature:

In benzene-d6; at -35 - 20 ℃; for 0.0833333h; Inert atmosphere; Glovebox;

DOI:10.1016/j.poly.2018.09.062

upstream raw materials:

lithium aluminium tetrahydride

dicarbonylcyclopentadienyliodoiron(II)

diphenyl(methyl)phosphine

sodium tetrahydroborate

Downstream raw materials:

(η(5)-MeC5H4)Fe(CO)(H)(PPh2Me)