triphenylgermylmethylidynetris(tert-butoxy)tungsten

Base Information

Chemical Name:triphenylgermylmethylidynetris(tert-butoxy)tungsten
CAS No.:467252-84-2
Molecular Formula:C₃₁H₄₂GeO₃W
Molecular Weight:719.113
Hs Code.:

Synonyms:triphenylgermylmethylidynetris(tert-butoxy)tungsten

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Chemical Property of triphenylgermylmethylidynetris(tert-butoxy)tungsten

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Technology Process of triphenylgermylmethylidynetris(tert-butoxy)tungsten

There total 1 articles about triphenylgermylmethylidynetris(tert-butoxy)tungsten which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.5%

: 57125-20-9
ditungsten hexa-tert-butoxide

: 467252-86-4
(C₆H₅)3GeCC(C₃H₇)

: 467252-84-2
triphenylgermylmethylidynetris(tert-butoxy)tungsten

Guidance literature:: In pentane; using Schlenk techniques; addn. of soln. of Ph3GeCCC3H7 in pentane to soln. of (t-C4H9O)6W2 in pentane; holding at 20°C for 1 h; evapn. in vac., vac. sublimation, recrystn. from pentane solid residue after sublimation, elem. anal.;

Reference yield: 95.0%

: 467252-84-2
triphenylgermylmethylidynetris(tert-butoxy)tungsten

: 7412-67-1
neopentyl lithium

: triphenylgermylmethylidyne-tris(neopentyl)tungsten

Guidance literature:: In diethyl ether; byproducts: lithium tert-butoxide; Schlenk technique, under vac.; soln. of lithium compd. in Et2O added to soln. of tungsten compd. in Et2O at 0°C, mixt. slowly heated to room temp.; evapn. under vac., residue extd. with pentane, extract evapd.; elem. anal.;
DOI:10.1007/s11172-006-0240-0

Reference yield: 93.0%

: 7647-01-0,15364-23-5
hydrogenchloride

: 467252-84-2
triphenylgermylmethylidynetris(tert-butoxy)tungsten

: 695197-02-5
((C₆H₅)3GeCH)WCl₂(OC(CH₃)3)2

: 75-65-0
tert-butyl alcohol

Guidance literature:: In pentane; standard Schlenk techniques; gaseous HCl (2 equiv.) condensed into soln.of W complex in pentane at -78°C; warmed to room temp.; solvent and volatiles removed in vac.; recrystd. from pentane; elem. anal.;
DOI:10.1016/j.jorganchem.2003.12.043