C₃₉H₆₂O₆Si₂

Base Information

• Chemical Name: C₃₉H₆₂O₆Si₂
• CAS No.: 219780-47-9
• Molecular Formula: C₃₉H₆₂O₆Si₂
• Molecular Weight: 683.089
• Mol file: 219780-47-9.mol

Synonyms:C₃₉H₆₂O₆Si₂

Chemical Property of C₃₉H₆₂O₆Si₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₉H₆₂O₆Si₂

There total 11 articles about C₃₉H₆₂O₆Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

di-tert-butylchlorosilane (56310-18-0) → C39H62O6Si2 (219780-47-9)

Guidance literature:

Multi-step reaction with 7 steps

1: BuLi / tetrahydrofuran / -78 - 0 °C

2: DIBAL / CH₂Cl₂ / -78 °C

3: 2,6-lutidine / CH₂Cl₂ / -23 °C

4: O₂, TPP / CH₂Cl₂ / Irradiation

5: Bu₃SnH, AIBN / benzene / Heating

6: H₂ / Pd/C / ethanol

7: CSA / CH₂Cl₂ / -23 °C

With 2,6-dimethylpyridine; n-butyllithium; 2,2'-azobis(isobutyronitrile); camphor-10-sulfonic acid; hydrogen; oxygen; tri-n-butyl-tin hydride; thiamine diphosphate; diisobutylaluminium hydride; palladium on activated charcoal; In tetrahydrofuran; ethanol; dichloromethane; benzene;

DOI:10.1021/ja9824932

Reference yield:

(S)-1-Hydroxy-4,6,6-trimethyl-5-[1-phenylsulfanyl-meth-(E)-ylidene]-3-triisopropylsilanyloxy-cyclohex-3-enecarbaldehyde (162084-46-0) → C39H62O6Si2 (219780-47-9)

Guidance literature:

Multi-step reaction with 9 steps

1: 1.) t-BuMgCl / 1.) THF, -78 deg C, 2.) THF, -78 deg C

2: 1.) (MeBO)3, pyridine, 2.) TiCl₂(OiPr)2, 3.) pinacol, DMAP

3: BuLi / tetrahydrofuran / -78 - 0 °C

4: DIBAL / CH₂Cl₂ / -78 °C

5: 2,6-lutidine / CH₂Cl₂ / -23 °C

6: O₂, TPP / CH₂Cl₂ / Irradiation

7: Bu₃SnH, AIBN / benzene / Heating

8: H₂ / Pd/C / ethanol

9: CSA / CH₂Cl₂ / -23 °C

With pyridine; 2,6-dimethylpyridine; dmap; n-butyllithium; 2,3-dimethyl-2,3-butane diol; titanium(IV) dichlorodiisopropylate; 2,2'-azobis(isobutyronitrile); Trimethylboroxine; camphor-10-sulfonic acid; tert-butylmagnesium chloride; hydrogen; oxygen; tri-n-butyl-tin hydride; thiamine diphosphate; diisobutylaluminium hydride; palladium on activated charcoal; In tetrahydrofuran; ethanol; dichloromethane; benzene;

DOI:10.1021/ja9824932

Reference yield:

C21H21LiO2 → C39H62O6Si2 (219780-47-9)

Guidance literature:

Multi-step reaction with 9 steps

1: 1.) t-BuMgCl / 1.) THF, -78 deg C, 2.) THF, -78 deg C

2: 1.) (MeBO)3, pyridine, 2.) TiCl₂(OiPr)2, 3.) pinacol, DMAP

3: BuLi / tetrahydrofuran / -78 - 0 °C

4: DIBAL / CH₂Cl₂ / -78 °C

5: 2,6-lutidine / CH₂Cl₂ / -23 °C

6: O₂, TPP / CH₂Cl₂ / Irradiation

7: Bu₃SnH, AIBN / benzene / Heating

8: H₂ / Pd/C / ethanol

9: CSA / CH₂Cl₂ / -23 °C

With pyridine; 2,6-dimethylpyridine; dmap; n-butyllithium; 2,3-dimethyl-2,3-butane diol; titanium(IV) dichlorodiisopropylate; 2,2'-azobis(isobutyronitrile); Trimethylboroxine; camphor-10-sulfonic acid; tert-butylmagnesium chloride; hydrogen; oxygen; tri-n-butyl-tin hydride; thiamine diphosphate; diisobutylaluminium hydride; palladium on activated charcoal; In tetrahydrofuran; ethanol; dichloromethane; benzene;

DOI:10.1021/ja9824932

upstream raw materials:

benzaldehyde dimethyl acetal

C₃₂H₅₈O₆Si₂

di-tert-butylchlorosilane

(S)-1-Hydroxy-4,6,6-trimethyl-5-[1-phenylsulfanyl-meth-(E)-ylidene]-3-triisopropylsilanyloxy-cyclohex-3-enecarbaldehyde

Downstream raw materials:

C₄₀H₆₄O₆Si₂

C₃₈H₅₁BO₆Si

C₃₂H₃₇BO₆

2’-TES-7-TROC-taxol