(3,5-diethynylphenol dibenzo[24]crown-8 carboxylate(-2H))(Pt(triethylphosphine)2(triflate))2

Base Information

Chemical Name:(3,5-diethynylphenol dibenzo[24]crown-8 carboxylate(-2H))(Pt(triethylphosphine)2(triflate))2
CAS No.:1020182-79-9
Molecular Formula:C₆₁H₉₄F₆O₁₆P₄Pt₂S₂
Molecular Weight:1775.59
Hs Code.:

Synonyms:(3,5-diethynylphenol dibenzo[24]crown-8 carboxylate(-2H))(Pt(triethylphosphine)2(triflate))2

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Chemical Property of (3,5-diethynylphenol dibenzo[24]crown-8 carboxylate(-2H))(Pt(triethylphosphine)2(triflate))2

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Technology Process of (3,5-diethynylphenol dibenzo[24]crown-8 carboxylate(-2H))(Pt(triethylphosphine)2(triflate))2

There total 1 articles about (3,5-diethynylphenol dibenzo[24]crown-8 carboxylate(-2H))(Pt(triethylphosphine)2(triflate))2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1020182-78-8
Pt₂I₂(3,5-diethynylphenol dibenzo[24]crown-8 carboxylate(-2H))(triethylphosphine)4

: 2923-28-6
silver trifluoromethanesulfonate

: 1020182-79-9
(3,5-diethynylphenol dibenzo[24]crown-8 carboxylate(-2H))(Pt(triethylphosphine)2(triflate))2

Guidance literature:: In dichloromethane; byproducts: AgI; addn. of silver triflate to CH2Cl2 soln. of platinum compd., keeping for4 h at room temp.; filtration, concg., addn. of diethyl ether, isolation of ppt., elem. anal.;
DOI:10.1021/ja711502t

Reference yield: 96.0%

: 6918-15-6
di-pyridin-4-yl-methanone

: 1020182-79-9
(3,5-diethynylphenol dibenzo[24]crown-8 carboxylate(-2H))(Pt(triethylphosphine)2(triflate))2

: [Pt₂(3,5-diethynylphenol dibenzo[24]crown-8 carboxylate(-2H))(triethylphosphine)4]3(di-2-pyridyl ketone)3(triflate)6

Guidance literature:: In dichloromethane-d2; addn. of CD2Cl2 soln. of 1 equiv. of pyridine deriv. to CD2Cl2 soln. of platinum compd. for 15 min, stirring for 30 min at room temp.; evapn., elem. anal.;
DOI:10.1021/ja711502t

Reference yield: 96.0%

: 553-26-4
4,4'-bipyridine

: 1020182-79-9
(3,5-diethynylphenol dibenzo[24]crown-8 carboxylate(-2H))(Pt(triethylphosphine)2(triflate))2

: [Pt₁₂(3,5-diethynylphenol dibenzo[24]crown-8 carboxylate(-2H))6(triethylphosphine)24(4,4'-bipyridyl)6](triflate)12

Guidance literature:: In dichloromethane-d2; addn. of CD2Cl2 soln. of pyridine deriv. to CD2Cl2 soln. of platinum compd. for 10 min, stirring for 30 min at room temp.; evapn., elem. anal.;
DOI:10.1021/ja711502t