p-trifluoroacetamidophenyl 2,3-di-O-acetyl-6-O-benzyl-4-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-α-D-galactopyranoside

Base Information

Chemical Name:p-trifluoroacetamidophenyl 2,3-di-O-acetyl-6-O-benzyl-4-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-α-D-galactopyranoside
CAS No.:85906-30-5
Molecular Formula:C₅₉H₆₀F₃NO₁₄
Molecular Weight:1064.12
Hs Code.:

Synonyms:p-trifluoroacetamidophenyl 2,3-di-O-acetyl-6-O-benzyl-4-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-α-D-galactopyranoside

Suppliers and Price of p-trifluoroacetamidophenyl 2,3-di-O-acetyl-6-O-benzyl-4-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-α-D-galactopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of p-trifluoroacetamidophenyl 2,3-di-O-acetyl-6-O-benzyl-4-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-α-D-galactopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of p-trifluoroacetamidophenyl 2,3-di-O-acetyl-6-O-benzyl-4-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-α-D-galactopyranoside

There total 10 articles about p-trifluoroacetamidophenyl 2,3-di-O-acetyl-6-O-benzyl-4-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-α-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 25320-59-6
tetra-O-benzyl glucopyranosyl chloride

: 85906-29-2
p-trifluoroacetamidophenyl 2,3-di-O-acetyl-6-O-benzyl-α-D-galactopyranoside

: 85906-30-5
Acetic acid (2R,3R,4S,5S,6R)-3-acetoxy-6-benzyloxymethyl-2-[4-(2,2,2-trifluoro-acetylamino)-phenoxy]-5-((2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-4-yl ester

: 85906-30-5
p-trifluoroacetamidophenyl 2,3-di-O-acetyl-6-O-benzyl-4-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-α-D-galactopyranoside

Guidance literature:: With 2,4,6-trimethyl-pyridine; silver trifluoromethanesulfonate; In dichloromethane; toluene; for 0.25h; Ambient temperature;
DOI:10.1016/0008-6215(83)88201-9

Reference yield: 51.0%

: 25320-59-6
tetra-O-benzyl glucopyranosyl chloride

: 85906-29-2
p-trifluoroacetamidophenyl 2,3-di-O-acetyl-6-O-benzyl-α-D-galactopyranoside

: 85906-30-5
Acetic acid (2R,3R,4S,5S,6R)-3-acetoxy-6-benzyloxymethyl-2-[4-(2,2,2-trifluoro-acetylamino)-phenoxy]-5-((2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-4-yl ester

: 85906-30-5
p-trifluoroacetamidophenyl 2,3-di-O-acetyl-6-O-benzyl-4-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-α-D-galactopyranoside

Guidance literature:: With 2,4,6-trimethyl-pyridine; silver trifluoromethanesulfonate; In dichloromethane; toluene; for 0.25h; Ambient temperature;
DOI:10.1016/0008-6215(83)88201-9

Reference yield:

: 85906-28-1
p-nitrophenyl 2,3-di-O-acetyl-4,6-O-benzylidene-α-D-galactopyranoside

: 85906-30-5
Acetic acid (2R,3R,4S,5S,6R)-3-acetoxy-6-benzyloxymethyl-2-[4-(2,2,2-trifluoro-acetylamino)-phenoxy]-5-((2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-4-yl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) hydrogen / 1.) 5 percent Pd/C / 1.) ethyl acetate; 2.) pyridine, 30 min, r.t.

2: 76 percent / sodium cyanoborohydride, hydrogen chloride / tetrahydrofuran; diethyl ether

3: 25 percent / silver triflate, 2,4,6-trimethylpyridine / toluene; CH₂Cl₂ / 0.25 h / Ambient temperature

With 2,4,6-trimethyl-pyridine; hydrogenchloride; hydrogen; silver trifluoromethanesulfonate; sodium cyanoborohydride; palladium on activated charcoal; In tetrahydrofuran; diethyl ether; dichloromethane; toluene;
DOI:10.1016/0008-6215(83)88201-9